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Journal : Eksergi: Chemical Engineering Journal

Penerapan Lima Model Kesetimbangan Adsorpsi Isoterm pada Adsorpsi Ion Logam Chrom VI oleh Zeolit Syarifah Aini; Supratikno Supratikno
Eksergi Vol 15, No 2 (2018): Vol. 15 No.2 (2018)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v15i2.2385

Abstract

Chrom VI metal ion include heavy metal waste which needs further processing using adsorbent. Zeolite is a suitable adsorbent for absorbing strong affinity chrom VI metal ions because zeolite is a natural mineral that has an active surface area per unit of mass and power. The purpose of this study was to determine a suitable model for the equilibrium adsorption of chrom VI metal ion by zeolite along with their parameter values, and to determine the optimal zeolite absorption against chrom VI metal ion. This study uses the method of applying the isotherm adsorption equilibrium model which includes 5 equations namely Linear Adsorption (Henry's Law), Freundlich Isotherm Adsorption, Langmuir Isoterm Adsorption, Brunauer-Emmett-Teller Isotherm (BET), Sigmoidal Chapman Equation. From these five models, data fitting is done to find models that are closer to the data. Data matching is done by minimizing the Matlab program. The results showed that the suitable model is the BET Isotherm Adsorption model with parameter values, namely the BET isotherm adsorption constant value (CBET) of 0.5183 l/mg, the maximum capacity of the adsorbent at equilibrium theoretical (qs) is 149.9977 mg/g and the saturated adsorbate concentration in the monolayer (Cs) is 184.1691 mg l.
Optimization of Coagulant Dosage for Suko River Water Treatment syarifah aini; H.D. Wahyudi; Kukuh Priyono
Eksergi Vol 18, No 1 (2021)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v0i0.4497

Abstract

Sungai Suko, Drono village, Ngawen sub-district, Klaten district, is located near residential area and tofu factory, the possibility of water contamination is quite high, which is caused by household waste. This river water can be processed into clean water by a coagulation process of the Jar Test method using coagulant alum, PAC and chlorine. The purpose of this study was to determine the optimum dose of coagulant in processing Suko river water into clean water using the Jar test method and knowing which coagulant is most suitable for processing the Suko river water into clean water. This research method is to use the Jar Test experiment to determine the optimum coagulant dose in processing Suko river water into clean water. The quality of the water samples before the experiment were tested which included the physical parameters, i.e. temperature, color, odor, and turbidity, also the chemical parameters, i.e. Fe, hardness, CO2, alkalinity, pH, COD, BOD, then the experimental results will determine the level of water clarity. The results showed that the optimum alum content in the experiment was 120 ppm by adding 6 mL of alum to 500 mL of water, the optimum level of PAC in the experiment is 200 ppm by adding 10 mL of PAC to 500 mL of water, and the optimum chlorine level in the experiment is 160 ppm by adding 8 mL of chlorine to 500 mL of water.