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Ahmad Marzuki
Sebelas Maret University
Education Materials Science & Nanotechnology Physics

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Absorption Spectra Comparison of Tm/Ho-Codoped Bototellurite Glasses Azmi Saraswati; Ahmad Marzuki; Venty Suryanti
Journal of Physics: Theories and Applications Vol 5, No 2 (2021): Journal of Physics: Theories and Applications
Publisher : Universitas Sebelas Maret

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/jphystheor-appl.v5i2.53809

Abstract

This paper presents a comparison study of absorption spectra of borotellurite glasses with compostion: 20TeO2 – 15Bi2O3 – 3TiO2 – (4-x) Na2CO3 – 1Tm2O3 - xHo2O3 where x = 0; 0.5; 1; 1.5; 2; 2.5 (mol%). All glasses are fabricated using melt quenching method. Absorption spectra were recorded at room temperature in the spectral range of 200 – 1100 nm. Within this range, glass with x = 0 mol % of Ho2O3 shows 2 absorption peaks which corresponds to electronics transition from 3H6 to state to 3F3 and 3H4.   For x = 0.5; 1; 1.5; 2; 2.5 (mol%), nine absorption peaks corresponding to electronics transition from 3H6 to state to 5G5, 5G6, 1G4, 1G4, 5F3, 5F4, 5F5, 3F3, and 3H4 are shown. It is shown that absorption at 680 nm and 790 are insensitive to the addition of Ho2O3 in contrast to that at 580 nm and 650 nm.
Impact of Nd2O3 on physical properties of lead borate glass system Ahmad Marzuki; Retno Willy Astuti; Devara Ega Fausta; Fransisca Indraningsih Kasy; Melya Ayu Mahasindi
Journal of Physics: Theories and Applications Vol 7, No 2 (2023): Journal of Physics: Theories and Applications
Publisher : Universitas Sebelas Maret

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/jphystheor-appl.v7i2.71762

Abstract

The Nd2O3 doped lead borate glass with composition 45B2O3-(40-x)PbO-11ZnO-4Na2O-xNd2O3 (x=0; 0.5; 1.0; 1.5; 2.0; 2.5) mol% were fabricated using melt quenching method at 950oC for 35 minutes. The characterization of physical properties of glasses doped Nd2O3 were measured by density (ρ) based on the Archimedes principle. The other physical parameters such as molar volume (Vm), oxygen packing density (OPD), polaron radius (rp), ionic radius (ri), field strength (F), molar refraction (Rm), and metallization (Mn) were calculated using equation which derived from density. According to the measurement, the density of glasses decreased from 5.774 to 4.527 gr/cm3 while molar volume oppositely increased from 23.17 to 30.18 cm3/mol due to  atomic mass of Nd (144.24) smaller than Pb (207.2). Along with the increase of molar volume, there were decreasing of the OPD, the polar radius (1.731 －1.095) Å and the ion radius (4.296－2.717) Å iof glasses Meanwhile, the field strength and metallization properties of the glasses  increased as a result of the reduction rp and ri. The investigation of molar refractive shows an increasing trend because the addition of the concentration Nd2O3.
Co-Authors Azmi Saraswati Devara Ega Fausta Fransisca Indraningsih Kasy Melya Ayu Mahasindi Retno Willy Astuti Venty Suryanti