Reaktor
Volume 18 No. 1 March 2018

THE KINETICS OF CaO ASSISTED PATTUKKU CHARCOAL STEAM GASIFICATION

Takdir Syarif (Department of Chemical Engineering, Faculty of Industrial Technology UMI Makassar)
H Sulistyo (Department of Chemical Engineering Faculty of Engineering Gadjah Mada Unuversity Yogyakarta)
Wahyudi B Sediawan (Department of Chemical Engineering Faculty of Engineering Gadjah Mada University Yogyakarta)
B Budhijanto (Department of Chemical Engineering Faculty of Engineering Gadjah Mada University Yogyakarta)



Article Info

Publish Date
28 May 2018

Abstract

Abstract Coal is a solid fuel that can be converted into syngas through gasification process. To obtain optimum gasification process design and operation, in-depth understanding of the influential parameters is required. This study aims to investigate the effect of temperature on the gasification process and to obtain its kinetics parameters. The study was carried out in a tubular reactor equipped with a heater and a condenser. Steam was used as gasifying agent, while CaO was employed as a CO2 adsorbent. The charcoal from coal was subjected to gasification at temperatures of 600°C, 700°C, and 800°C. The ratio of charcoal and CaO was 1:1. The gasification process lasted for 60 minutes with gas sample was taken every 15 minutes for composition analysis. The results showed that a temperature increase of 100°C caused a proportional increase of conversion of about 75% higher. The value of activation energy (Ea) and exponential factor (ko) were 46.645kJ/mole and 328.3894/min, respectively. For mass transfer parameters, values of activation energy for surface diffusion (Es) and surface diffusivity factor (as) were 81.126 kJ/mole and 0.138/min, respectively. Keywords: gasification; mathematical model; Pattukku coal char; steam; Thin Reaction Zone Model

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Journal Info

Abbrev

reaktor

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Control & Systems Engineering Energy Materials Science & Nanotechnology

Description

Reaktor invites contributions of original and novel fundamental research. Reaktor publishes scientific study/ research papers, industrial problem solving related to Chemical Engineering field as well as review papers. The journal presents paper dealing with the topic related to Chemical Engineering ...