Molekul: Jurnal Ilmiah Kimia
Vol 3, No 1 (2008)

STUDI DEGRADASI ZAT PEWARNA AZO, METIL ORANYE MENGGUNAKAN FERRAT (FeO42-)

Dian Windy Dwiasi (Program Studi Kimia, Fakultas Sains dan Teknik Unsoed Purwokerto)
Mardiyah Kurniasih (Program Studi Kimia, Fakultas Sains dan Teknik Unsoed Purwokerto)



Article Info

Publish Date
01 May 2008

Abstract

Synthesis of ferrate and its application to azo dyes degradation have been investigated. The synthesis was carried out by reacting Fe(NO3)3 solution with NaOCl in alkaline condition. Oxidation reaction of azo dyes was carried out by adjusting the molar ratio of ferrate to azo dyes. When ferrate reacted with azo dyes, its absorbance was monitored using UV-Vis spectrophotometer at pH condition that had been optimized. Kinetics study for azo dyes degradation was carried out at the absorbance maximum of azo dyes, as a function of time. Ferrate can oxidize azo dyes, methyl oranye effectively in optimum pH of 9.6. With the molar ratio of ferrate/azo dyes 5/1, it showed that the percentages of methyl oranye degradation reached 100%. The azo dyes degradation followed first order of kinetics. Analysis using UV-Vis spectrofotometry suggests that the products of azo dyes degradation are nitrate, ammonia, and benzene. This results showed that ferrate is an alternative and green oxidizing agent which can be used for azo dyes degradation.

Copyrights © 2008






Journal Info

Abbrev

jm

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

MOLEKUL is a peer-reviewed journal of chemistry published by the Department of Chemistry, Faculty of Mathematics and Natural Sciences, Jenderal Soedirman University, Indonesia. Publishing frequency 2 issues per year, on May and November. This Journal encompasses all branches of chemistry and its ...