Metal Indonesia
Vol 42, No 1 (2020): Metal Indonesia

Recovery of Rare Earth Elements and Yitrium from non-Magnetic Coal Fly Ash using Acetic Acid Solution

Hotden Manurung (Departemen Teknik Kimia (Sustainable Mineral Processing Research Group), Fakultas Teknik, Universitas Gadjah Mada)
Widya Rosita (Departemen Teknik Kimia (Sustainable Mineral Processing Research Group), Fakultas Teknik, Universitas Gadjah Mada)
I Made Bendiyasa (Departemen Teknik Kimia (Sustainable Mineral Processing Research Group), Fakultas Teknik, Universitas Gadjah Mada)
Agus Prasetya (Departemen Teknik Kimia (Sustainable Mineral Processing Research Group), Fakultas Teknik, Universitas Gadjah Mada)
Ferian Anggara (Departemen Teknik Geologi, Fakultas Teknik, Universitas Gadjah Mada)
Widi Astuti (Balai Penelitian Teknologi Mineral, Lembaga Ilmu Pengetahuan Indonesia (LIPI))
Dagus Resmana Djuanda (Balai Besar Logam dan Mesin - Metal Industries Development Center (MIDC), Kementerian Perindustrian)
Himawan Tri Bayu Murti Petrus (Departemen Teknik Kimia (Sustainable Mineral Processing Research Group), Fakultas Teknik, Universitas Gadjah Mada Unconventional Geo-resources Research Center, Faculty of Engineering, Universitas Gadjah Mada)



Article Info

Publish Date
30 Jun 2020

Abstract

The increasing need of REY has been observed in industries such as catalyst industry, metallurgy, military, health and renewable energy resources. REY such as Ce, Nd, Y, and Eu has a prominent evidence to improve material properties such as high electropositive, good conductivity and renewable energy. Due to this increasing need of REY, exploration of alternative source has been conducted. One of the promising alternative sources is coal fly ash. The conventional method to recover REY from coal fly ash using inorganic acids is harmful to the environment. Thus, the exploration of REY extraction from coal fly ash using organic acid has been proposed in this study. The leaching agent was acetic acid applied for all operating condition. Regarding to the mineralization of REY in the form of siliceous minerals (non-magnetic coal fly ash). Silicate digestion was conducted using sodium hydroxide 8 M with solid-to-liquid of 25% to decompose the siliceous mineral. Further, the REY bound siliceous mineral will change to REY(OH)3. Temperature as one of the operating conditions was varied. The maximum recovery of leaching 20.58 %, 43.53 %, 17.38%, 40.96 %, 18.45 % and 32.74 % were achieved for Ce, Dy, La, Nd, Y and Yb respectively at temperature of 90 0C pH 1.74 and 120 minutes. For some metals, increasing the temperature higher than 70 0C does not provide any significant effect for REY recovery such as La and Ce.

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