JURNAL KIMIA SAINS DAN APLIKASI
Vol 22, No 6 (2019): Volume 22 Issue 6 Year 2019

Effect of Sodium Periodate on the Adsorption Capacity of Silica-Lignin from Rice Husk on Chromium(VI)

Yati B. Yuliyati (Chemistry Department, Faculty of Mathematics and Science, Universitas Padjadjaran Bandung)
Solihudin Solihudin (Chemistry Department, Faculty of Mathematics and Science, Universitas Padjadjaran Bandung)
Atiek Rostika Noviyanti (Chemistry Department, Faculty of Mathematics and Science, Universitas Padjadjaran Bandung)



Article Info

Publish Date
30 Nov 2019

Abstract

Reactive groups such as silanol, hydroxyl, and carbonyl groups in silica-lignin composites play a role in binding to chromium(VI) ions. The activation of functional groups in silica-lignin can be increased by the addition of an activator such as sodium periodate, which can also oxidize the lignin monomer (guaiasil) to ortho-quinone. This study aimed to obtain silica-lignin composites from rice husks activated by sodium periodate with a high surface area. Composite absorption was tested on chromium(VI) adsorption. Silica-lignin isolation was carried out by using the sol-gel method at concentrations of sodium hydroxide 5, 10, 15, and 20% (b/b). Silica-lignin activated with sodium periodate 10% (b/b) had the smallest particle size of about 8μm, with a surface area of 14.0888 m2.g-1 and followed Halsey isotherm adsorption model, with an adsorption capacity of 0.3054 mg.g-1.

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Journal Info

Abbrev

ksa

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Engineering

Description

urnal Kimia Sains dan Aplikasi (p-ISSN: 1410-8917) and e-ISSN: 2597-9914) is published by Department of Chemistry, Diponegoro University. This journal is published four times per year and publishes research, review and short communication in field of ...