Indonesian Journal of Pure and Applied Chemistry
Vol 1, No 3 (2018)

ADSORPTION OF Pb(II) BY POLYANILINE/SILICA GEL COMPOSITE: KINETICS AND ISOTHERM STUDIES

Mas Inda Putrinesia (Jurusan Kimia, Fakultas MIPA, Universitas Tanjungpura, Kalimantan Barat)
Nurlina Nurlina (Jurusan Kimia, Fakultas MIPA, Universitas Tanjungpura, Kalimantan Barat)
Winda Rahmalia (Jurusan Kimia, Fakultas MIPA, Universitas Tanjungpura, Kalimantan Barat)



Article Info

Publish Date
12 Jul 2019

Abstract

Research on the study of kinetics and isotherm adsorption of Pb(II) by polyaniline/silica gel (PANI/SiO2) composite from glass waste has successfully been done. The polymerization of silica gel was prepared by sol-gel process. Meanwhile, PANI/SiO2 composite was prepared using sulfuric acid (H2SO4) as its dopants and hydrogen peroxide (H2O2) for oxidation process. Composition of oxide compound in PANI/SiO2 composite was analyzed by X-Ray Fluorosence (XRF) and Gas Sorption Analyzer (GSA). Adsorption of Pb(II) was carried out by contacting PANI/SiO2 with Pb(NO3)2 solution for 20, 40, 60 and 80 minutes, with concentrations of 150, 200, 250, 300, 350 and 400 mg/L. The optimum contact time was reached at 40 minutes. This adsorption followed pseudo-second order model with R2= 0.996. The first optimum adsorption capacity was reached in the concentration of 250 mg/L. Isotherm adsorption followed Langmuir models with R2= 0.954 (monolayer capacity= 51.02 mg/g).

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Journal Info

Abbrev

IJoPAC

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemistry

Description

Indonesian Journal of Pure and Applied Chemistry (IJoPAC) was first established in 2018 as a scientific journal that accommodates researchers and education practitioners to publish scientific work and research results which are the results of experiments or literature studies in the field of ...