Jurnal Kimia Mulawarman
Vol 8 No 1 (2010)

PENGARUH PENAMBAHAN INISIATOR DIKUMIL PEROKSIDA DAN DIVINILBENZENA SEBAGAI CROSLINK PADA KOMPATIBILITAS RASIO CAMPURAN POLIETILENA DAN KARET ALAM SIR 3L

Amir Hamzah Siregar (Departemen Kimia FMIPA USU Medan.)



Article Info

Publish Date
24 Feb 2016

Abstract

The research about  the influence of adding initiator dicumyl peroxide and divinylbenzene as crosslink agent on the compatibility blending rasio polyethylene and natural rubber SIR 3L   has been carried out. Blending is done in two steps, the first step was without the addition of divinylbenzene, polyethylene/natural rubber SIR 3L/dicumyl peroxide (w/w) 50 g : 50 g : 1phr, 2phr, and 3phr. The second step was by the addition of divinylbenzene, polyethylene/natural rubber SIR 3L/divinylbenzene/dicumyl peroxide (w/w) 50 g : 50 g : 1phr :1phr, 2phr : 1phr, 3phr : 1phr, 1phr : 2 phr, 2phr : 2phr, 3phr : 2phr, 1phr : 3phr, 2phr : 3phr, dan 3phr : 3phr. To determine the quality of yielded composites,  the tensile test analysis was done, obtained the increasing concentration without divinylbenzene, maximum at variation of concentration polyethylene/natural rubber SIR 3L/dicumyl peroxide is 2 phr is tensile strength and elasticity was 2.20 kgf/mm2 and 12.29%, and by addition of divinylbenzene  obtained the increasing maximum at variation of concentration polyethylene/natural rubber SIR 3L/divinylbenzene/dicumyl peroxide 3phr : 2phr, the tensile strength and elasticity was 3.31 kgf/mm2 and 28.99%. From the SEM analysis result was obtained that the addition of divinylbenzene could improved the composite’s surface so that  become more flatten and homogeneous. From the functional group analysis FT-IR showed that the mixture of divinylbenzene and polyethylene/natural rubber SIR 3L/dicumyl peroxide were just physical interaction. Keyword: peroxside,  Divinyl benzene, Poly Ethylene, Natural rubber (SIR 3 L) Blending

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Journal Info

Abbrev

JKM

Publisher

Subject

Chemistry

Description

Journal of Kimia Mulawarman is a peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry, including educational chemistry and applied ...