Reaktor
Volume 20 No.3 September 2020

Solely Cellulose-based Adsorbent Derived from Oil Palm Empty Fruit Bunches for Dye Removal

Athanasia Amanda Septevani (Research Center for Chemistry Indonesian Institute of Sciences)
Farhan Riza Afandi (Research Center for Chemistry, Indonesian Institute of Sciences, South Tangerang, Indonesia)
Yulianti Sampora (Research Center for Chemistry, Indonesian Institute of Sciences, South Tangerang, Indonesia)
Melati Septiyanti (Research Center for Chemistry, Indonesian Institute of Sciences, South Tangerang, Indonesia)
Yenni Apriliany Devy (Research Center for Chemistry, Indonesian Institute of Sciences, South Tangerang, Indonesia)
Aisah Resti Amelia (Eijkman Institute for Molecular Biology, Jakarta, Indonesia)
Dian Burhani (Research Center for Biomaterial, Indonesian Institute of Sciences, West Java, Indonesia)



Article Info

Publish Date
13 Oct 2020

Abstract

The purpose of this research is to determine the adsorption capability of micro and nano-cellulose derived from oil palm empty fruit bunch (EFB) as dye removal. Cellulose based adsorbents were successfully obtained from EFB in the form of microcellulose (eMC) via both delignification (D-eMC) and bleaching processes (B-eMC) as well as in nanocellulose (eNC) by using acid hydrolysis method and hence termed as delignified-eNC (D-eNC) and bleached-eNC (B-eNC) respectively. Dye adsorption test was carried out by UV-Spectrophotometer by comparing initial dye MO concentration (as a control solution) to the treated MO solution upon the addition of micro- and nano- cellulose based adsorbent. It was clear that the dye removal efficiency of micro-cellulose both D-eMC and B-eMC were lower than the nano-cellulose structures. The higher adsorptive capacity of nano-size cellulose compared to the micro-size cellulose was confirmed by the distinct presence of FTIR shifting peak of hydroxyl and sulfonyl groups. It was expected as the micro-size of cellulose would not be able to provide a good adsorptive capability of hydroxyl surface active agent to adsorb the dye. In the case of eNC, the result showed that D-eNC afforded a better dye adsorption than B-eNC. At the same concentration of eNC at 3 wt. %, D-eNC could adsorb at about 19.3% of MO while only 2.4% of MO could be removed by B-eNC. Finally, all of adsorbent could maintain pH and TDS within water quality specification. 

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Journal Info

Abbrev

reaktor

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Control & Systems Engineering Energy Materials Science & Nanotechnology

Description

Reaktor invites contributions of original and novel fundamental research. Reaktor publishes scientific study/ research papers, industrial problem solving related to Chemical Engineering field as well as review papers. The journal presents paper dealing with the topic related to Chemical Engineering ...