Molekul: Jurnal Ilmiah Kimia
Vol 16, No 1 (2021)

Isolation, Characterization and Application of Humin From Sumatran Peat Soils as Adsorbent for Naphtol Blue Black and Indigosol Blue Dyes

Maya Rahmayanti (Prodi Kimia, Fakultas Sains dan Teknologi, UIN Sunan Kalijaga)
Indah Nurhikmah (Prodi Kimia, Fakultas Sains dan Teknologi, UIN Sunan Kalijaga)
Feni Larasati (Prodi Kimia, Fakultas Sains dan Teknologi, UIN Sunan Kalijaga)



Article Info

Publish Date
28 Mar 2021

Abstract

Isolation, characterization and application of humin as adsorbent for naphtol blue black (NBB) and indigosol blue (IB) dyes has been carried out. Humin application in this study aims to obtain the optimum pH conditions and kinetics model for adsorption NBB and IB dyes onto humin. Humin was isolated from peat soils originating from Riau, Sumatra. The isolation method used was the alkaline extraction method and the characterization of humin using FTIR spectrophotometer. The total acidity, carboxylic groups and –OH phenolic groups of humin were determined quantitatively using the acid-base titration method. FTIR characterization indicated the presence of an –OH group which was indicated by the appearance of absorption at a wavelength of 3425.3 cm-1 and a stretching vibration of C=O from the –COOH group at a wavelength of 1705 cm-1. The quantitative calculation of the total acidity value, the content of the carboxylic group and the -OH group phenolics of humin were 508.47 cmol kg-1, 289.42 cmol kg-1 and 219.05 cmol kg-1, respectively. The optimum pH conditions for adsorption NBB and IB onto humin occurred at pH 5 and pH 2, respectively. The adsorption kinetics model of NBB and IB on humin followed the Ho kinetics model.

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Journal Info

Abbrev

jm

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

MOLEKUL is a peer-reviewed journal of chemistry published by the Department of Chemistry, Faculty of Mathematics and Natural Sciences, Jenderal Soedirman University, Indonesia. Publishing frequency 2 issues per year, on May and November. This Journal encompasses all branches of chemistry and its ...