JURNAL KIMIA SAINS DAN APLIKASI
Vol 24, No 6 (2021): Volume 24 Issue 6 Year 2021

MgO-supported Ni-Sn Catalysts: Characterization and Catalytic Properties for Aqueous-phase Catalytic Reforming of Glycerol

Kiky Corneliasari Sembiring (Research Center for Chemistry, National Research and Innovation Agency (BRIN), Serpong, Tangerang|National Research and Innovation Agency (BRIN)|Indonesia)
Anis Kristiani (Research Center for Chemistry, National Research and Innovation Agency Republic of Indonesia (BRIN), Kawasan Puspiptek, Serpong, South Tangerang|National Research and Innovation Agency (BRIN)|Indonesia)
Luthfiana Nurul Hidayati (Research Center for Chemistry, National Research and Innovation Agency (BRIN), Serpong, Tangerang|National Research and Innovation Agency (BRIN)|Indonesia)
Sudiyarmanto Sudiyarmanto (Research Center for Chemistry, National Research and Innovation Agency (BRIN), Serpong, Tangerang|National Research and Innovation Agency (BRIN)|Indonesia)
Fauzan Aulia (Research Center for Chemistry, National Research and Innovation Agency (BRIN), Serpong, Tangerang|National Research and Innovation Agency (BRIN)|Indonesia)
Asif Aunillah (Indonesian Agency for Agricultural Research and Development, Indonesian Ministry of Agriculture, Jakarta|Indonesian Agency for Agricultural Research and Development|Indonesia)



Article Info

Publish Date
31 Aug 2021

Abstract

The aqueous phase reforming (APR) of glycerol into value-added products, including H2 and alkanes, is environmentally green. In this work, the conversion of glycerol into syngas was demonstrated using MgO-supported Ni-Sn catalysts. Ni species is known for its capability of converting glycerol, but the activity towards water gas shift (WGS) reaction has not been satisfied. Loading Ni-Sn onto MgO has increased the catalyst basicity, which promotes a positive effect in WGS reaction. A series of bimetallic catalysts, impregnated Ni-Sn on MgO support, was prepared with various Ni-Sn loading amounts. To better understand the behavior of prepared catalysts, they were evaluated physio-chemically through XRD, BET, and FTIR. The catalytic activity test was performed for APR in a continuous flow reactor with aqueous glycerol 10 v-% as a feedstock at a reaction temperature of 250°C. As a result, the maximum hydrogen selectivity was obtained at about 73 v-%.

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Journal Info

Abbrev

ksa

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Engineering

Description

urnal Kimia Sains dan Aplikasi (p-ISSN: 1410-8917) and e-ISSN: 2597-9914) is published by Department of Chemistry, Diponegoro University. This journal is published four times per year and publishes research, review and short communication in field of ...