Science and Technology Indonesia
Vol. 7 No. 1 (2022): January

Layered Double Hydroxide/C (C=Humic Acid;Hydrochar) As Adsorbents of Cr(VI)

Patimah Mega Syah Bahar Nur Siregar (Magister Programme Graduate School of Mathematics and Natural Sciences, Sriwijaya University, Palembang 30139, Indonesia)
Alfan Wijaya (Magister Programme Graduate School of Mathematics and Natural Sciences, Sriwijaya University, Palembang 30139, Indonesia)
Amri (Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang 30139, Indonesia)
Juliana Putri Nduru (Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang 30139, Indonesia)
Nurlisa Hidayati (Graduate School of Faculty Mathematics and Natural Sciences, Sriwijaya University, Palembang 30139, Indonesia)
Aldes Lesbani (Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang 30139, Indonesia)
Risfidian Mohadi (Graduate School of Faculty Mathematics and Natural Sciences, Sriwijaya University, Palembang 30139, Indonesia)



Article Info

Publish Date
27 Jan 2022

Abstract

Layered double hydroxide (LDH) is known as a layered material that can be used as an adsorbent to remove pollutants from aqueous solutions. The use of layered double hydroxide as an adsorbent is not very effective due to its structure which is easily damaged so that it cannot be reused and its small surface area which results in a small adsorption capacity. This can be overcome by developing layered double hydroxide into a composite material. Modification of layered double hydroxide is done by using supporting materials in the form of humic acid and hydrochar. In this study the adsorbent was applied in the removal of Cr(VI) metal from aqueous solutions. The layered double hydroxide modification process was successfully carried out as seen from the XRD, FTIR, and BET analysis. XRD analysis shows the peaks that appear in Mg/Al-AH and Mg/Al-HC are peaks composed of their constituent materials, namely Mg/Al LDH, humic acid, and hydrochar. The vibrations that appear in Mg/Al-AH and Mg/Al-HC are vibrations originating from Mg/Al, humic acid, and hydrochar. The layered double hydroxide material composited with humic acid showed a surface area from 2.155 m2/g to 3.337 m2/g. The layered double hydroxide material composited with hydrochar showed a larger surface area than the Mg/Al LDH base material. The surface area increased 37 times, from 2.155 m2/g to 74.207 m2/g. The Mg/Al-AH composite showed the first adsorption ability of 89.064% and there was no significant decrease in the next cycle. The Mg/Al-HC composite showed adsorption ability in the first cycle which reached 97.079%, the ability to survive up to the fifth cycle with a final ability of 75.029%.

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Journal Info

Abbrev

JSTI

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Environmental Science Materials Science & Nanotechnology Physics

Description

An international Peer-review journal in the field of science and technology published by The Indonesian Science and Technology Society. Science and Technology Indonesia is a member of Crossref with DOI prefix number: 10.26554/sti. Science and Technology Indonesia publishes quarterly (January, April, ...