Automotive Experiences
Vol 4 No 1 (2021)

Synthesis of Bio-additive for Low Sulphur Diesel: Transesterification of Soybean Oil and Ethylene Glycol using K2CO3 Catalyst

Rhiby Ainur Basit Hariyanto (Institut Teknologi Sepuluh Nopember, Indonesia)
R. Arizal Firmansyah (Universitas Islam Negeri Walisongo, Indonesia)
R. Y. Perry Burhan (Institut Teknologi Sepuluh Nopember, Indonesia)
Yulfi Zetra (Institut Teknologi Sepuluh Nopember, Indonesia)



Article Info

Publish Date
13 Mar 2021

Abstract

The desulphurization process of diesel fuel is carried out to reduce the amount of SO2 emissions that can cause acid rain. However, the desulphurization process in diesel fuel not only removes the sulfur compounds but polyaromatic and polar compounds are also eliminated during this process. The loss of these two compounds can reduce the lubricity properties of diesel fuel. Therefore, it is necessary to add an additive compound that can increase the lubricity properties. In this research, 2-hydroxyethyl ester (HEE) was synthesized as an additive to increase the lubricity of diesel fuel. This compound was synthesized through the transesterification reaction of soybean oil and ethylene glycol with K2CO3 as the base catalyst. The composition of the synthesized additives was analyzed using the Gas Chromatography-Mass Spectrometry (GC-MS). Based on the results of GC-MS spectrum analysis, it is known that the 2-hydroxyethyl ester compound has been formed with a yield of 66.5% (relative to the area of the chromatogram peak). The HEE compound obtained is a mixture of 2 hydroxyethyl palmitate, 2 hydroxyethyl linoleate, 2 hydroxyethyl stearate, 2 hydroxyethyl arachidonate, 2 hydroxyethyl nervate, and 2 hydroxyethyl behenate.

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Journal Info

Abbrev

AutomotiveExperiences

Publisher

Subject

Aerospace Engineering Automotive Engineering Chemical Engineering, Chemistry & Bioengineering Control & Systems Engineering Electrical & Electronics Engineering Energy Materials Science & Nanotechnology Mechanical Engineering

Description

Automotive experiences invite researchers to contribute ideas on the main scope of Emerging automotive technology and environmental issues; Efficiency (fuel, thermal and mechanical); Vehicle safety and driving comfort; Automotive industry and supporting materials; Vehicle maintenance and technical ...