Journal of Engineering and Technological Sciences
Vol. 47 No. 5 (2015)

Partial Hydrogenation of Calophyllum Inophyllum Methyl Esters to Increase the Oxidation Stability

Joelianingsih Joelianingsih (Chemical Engineering Study Program, Institut Teknologi Indonesia, Jalan Raya Puspitek, Serpong, Tangerang Selatan 15320)
P. Putra (Chemical Engineering Study Program, Institut Teknologi Indonesia, Jalan Raya Puspitek, Serpong, Tangerang Selatan 15320)
A.W. Hidayat (Chemical Engineering Study Program, Institut Teknologi Indonesia, Jalan Raya Puspitek, Serpong, Tangerang Selatan 15320)
R. Fajar (Center for Thermodynamics Motor and Propulsion System, BPP Teknologi, Gdg 230 Kawasan Puspiptek Serpong, Tangerang Selatan 15314)



Article Info

Publish Date
30 Oct 2015

Abstract

Calophyllum inophyllum methyl esters have a low oxidation stability value (5-6 h) caused by high amounts of polyunsaturated fatty acid methyl esters (FAME), especially methyl linoleate. Partial hydrogenation was done to reduce the number of polyunsaturated FAME to transform them into mono-unsaturated. This was performed at 6 bar and 900 rpm with Pd/Al2O3 solid catalyst in a reactor with a capacity of 1 liter. The research purpose was to learn the effects of reaction temperature (80; 100; 120°C) and time (1; 1.5; 2 h) on the FAME composition. The optimum condition of the experiment was obtained at 120°C for 1 h, with 15.47 h as the oxidation stability value, 17.8°C as the cloud point value, and 51.17 as the cetane number. Under this condition, the methyl linoleate content decreased by 59.89% w/w (from 21.869% to 8,770% w/w) and methyllinoleate hydrogenated into methyl elaidate. Meanwhile, the methyl linolenate content decreased by 85,37% w/w (from 0.205% to 0.030% w/w) and methyl linolenate hydrogenated into methyl linolelaidate. These results show that the research met the following standards: a minimum oxidation stability value of 10 h in accordance with the World Wide Fuel Charter (WWFC) 2009, a maximum cloud point value of 18°C and a minimum cetane number 51 in accordance with SNI 7182-2012. The physical properties values of the Calophyllum inophyllum methyl esters were predicted using the empirical equations.

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Journal Info

Abbrev

JETS

Publisher

Subject

Engineering

Description

Journal of Engineering and Technological Sciences welcomes full research articles in the area of Engineering Sciences from the following subject areas: Aerospace Engineering, Biotechnology, Chemical Engineering, Civil Engineering, Electrical Engineering, Engineering Physics, Environmental ...