Jurnal Teknik Kimia USU
Vol. 2 No. 4 (2013): Jurnal Teknik Kimia USU

PEMANFAATAN ABU KULIT BUAH KELAPA SEBAGAI KATALIS PADA REAKSI TRANSESTERIFIKASI MINYAK SAWIT MENJADI METIL ESTER

Muhammad Yusuf Ritonga (Departemen Teknik Kimia, Fakultas Teknik Universitas Sumatera Utara)
Doni Hermanto Sihombing (Departemen Teknik Kimia, Fakultas Teknik Universitas Sumatera Utara)
Allen Rianto Sihotang (Departemen Teknik Kimia, Fakultas Teknik Universitas Sumatera Utara)



Article Info

Publish Date
27 Dec 2013

Abstract

Transesterification is the reaction to produce methyl esters in which this reaction’s catalyst involves coconut shell burnt ash at temperature of 550, 600, 650 °C for 8 hours and uses 1%, 2%, 3% (w/w) of ash. Ash used was dissolved in 75 ml of methanol to obtain potassium methoxide compound and was analyzed by AAS (Atomic Absorption Spectrophotometer) to determine potassium content. Palm oil involved in the processing stage of degumming with the addition of 0,6% (w/w) H3PO4 85% to remove gum then followed by an esterification reaction using 3,0% (w/w) H2SO498% as the catalyst to reduce FFA<1%. The temperature of transesterification reaction was at 65 °C for 2 hours, ratio of methanol: CPO 6:1 (n/n) and 500 rpm agitation. Quantitatively, the optimum yield of 81% methyl esters is gained with shell burnt ash at temperature of 600 ° C, 1% (w/w) of ash with the specification of methyl esters as density, kinematic viscosity and flash point are relatively conformed to SNI04-7182-2006 biodiesel and 92.99% purity methyl ester with 4.62% total glycerin,2.39% free glycerin based on GC (Gas Chromatography).

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Journal Info

Abbrev

jtk

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology

Description

Jurnal Teknik Kimia USU merupakan jurnal elektronik yang mempublikasikan karya ilmiah di bidang teknik kimia yang diterbitkan oleh Departemen Teknik Kimia, Fakultas Teknik, Universitas Sumatera Utara. Jurnal ini tidak terbatas pada mahasiswa dan dosen Universitas Sumatera Utara, tetapi terbuka untuk ...