Science and Technology Indonesia
Vol. 7 No. 3 (2022): July

Preparation of Hydrochar from Salacca zalacca Peels by Hydrothermal Carbonization: Study of Adsorption on Congo Red Dyes and Regeneration Ability

Mauizatul Hasanah (Department of Pharmacy, School of Pharmacy Bhakti Pertiwi, Palembang, 30128, Indonesia)
Alfan Wijaya (Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, South Sumatera, Indonesia)
Fitri Suryani Arsyad (Doctoral Program, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, Indonesia)
Risfidian Mohadi (Doctoral Program, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, Indonesia)
Aldes Lesbani (Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, South Sumatera, Indonesia)



Article Info

Publish Date
28 Jul 2022

Abstract

Hydrochar of Salacca zalacca peels (HC-SP) is prepared by hydrothermal carbonization treatment of Salacca zalacca peels (SP) obtained from local fruits at Palembang, South Sumatera, Indonesia, with the resulting yield weight reaching 90%. Materials are characterized using the XRD diffraction, FTIR spectrum, and SEM-EDX. The XRD pattern shows the characteristics of the formation of amorphous compounds. The FTIR spectrum confirms the presence of functional groups O-H, C-H, C=C, and C-O. Data of SEM-EDX show that materials have heterogeneous morphologies, form aggregates, and in HC-SP materials there is an increase in carbon content from the initial material. The capacity of SP in the congo red (CR) adsorption process is 33.003 mg/g and increases to 133.333 mg/g in HC-SP. The maximum dye adsorbed was achieved at pH 4. The adsorption kinetics followed PSO with the equilibrium adsorption occurring at 90 minutes, and the adsorption isotherm followed the Langmuir isotherm with the value of R2 closer to the value of 1. A positive 4H value indicated that the adsorption is an endothermic process. In contrast, an 4S value suggested that the degree of irregularity in the adsorption process is small in large concentrations. Based on data regeneration ability, materials of SP and HC-SP can be used in the three cycles regeneration process of the CR adsorption process. The adsorption process of CR occurs physically and chemically based on enthalpy values and FT-IR data after being adsorbed with CR.

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Journal Info

Abbrev

JSTI

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Environmental Science Materials Science & Nanotechnology Physics

Description

An international Peer-review journal in the field of science and technology published by The Indonesian Science and Technology Society. Science and Technology Indonesia is a member of Crossref with DOI prefix number: 10.26554/sti. Science and Technology Indonesia publishes quarterly (January, April, ...