Indonesian Journal of Electrical Engineering and Computer Science
Vol 27, No 3: September 2022

Ca9La(PO4)7:Eu2+,Mn2+: a radiation-adjustable phosphor usable for high-perfomance white light-emitting diodes

Phuc Dang Huu (Industrial University of Ho Chi Minh City)
Phung Ton That (Industrial University of Ho Chi Minh City)
Phan Xuan Le (Van Lang University)
Nguyen Le Thai (Nguyen Tat Thanh University)



Article Info

Publish Date
01 Sep 2022

Abstract

We used solid-condition processes to make a sequence of radiation-adjustable phosphors Eu2+/Mn2+ co-doped Ca9La(PO4)7 (shortened as CaLa:EM), which show a consistently variable hue from green to yellow and red via an efficient resonance-form energy transition as well as the strength of green and red radiations may be controllable through altering the Mn2+concentration. We examined the transition of energy (Eu2+®Mn2+) for CaLa:EM. It is proved to be a resonant kind using a dipole-quadrupole process, having power shift critical range calculated to be 11.36 Å by using the spectral overlap techniques. Mixing a 365 nm UV-InGaN chip as well as one phosphor combination containing (Ca0.98Eu0.005Mn0.015)9La(PO4)7 in yellow with BaMgAl10O17:Eu2+in blue produced a warming WLED having CIE color coordinates measured at (0.35, 0.31), better CRI value (Ra)measured at 91.5 along with smaller CCT value of 4,496 K.

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