Preparation of Zinc Oxide/Graphite Composite Using Solid-State Method as an Anode Material for Lithium-Ion Battery

Hendri Widiyandari (Department of Physics, Faculty of Sciences and Mathematics, Sebelas Maret University, Surakarta 57146|Sebelas Maret University|IndonesiaCentre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret, Surakarta 57146|Sebelas)
Hanaiyah Parasdila (Department of Physics, Faculty of Sciences and Mathematics, Sebelas Maret University, Surakarta 57146|Sebelas Maret University|Indonesia)
Anisa Surya Wijareni (Department of Metallurgical Engineering, Faculty of Mining and Petroleum Engineering, Bandung Institute of Technology, Bandung|Bandung Institute of Technology|Indonesia)

JURNAL KIMIA SAINS DAN APLIKASI
Vol 25, No 7 (2022): Volume 25 Issue 7 Year 2022

Lithium-ion batteries using zinc oxide (ZnO) as anode material had a high theoretical capacity of about 987 mAh/g. Unfortunately, ZnO capacity can drop below 200 mAh/g after only a few cycles. For that reason, graphite was added in this study due to its stable theoretical capacity of around 348-374 mAh/g to maintain the stability of lithium-ion battery capacity. Zinc oxide/graphite (ZnO/Graphite) was prepared using a solid-state method, in which ZnO and graphite were mortared until homogeneous with the mass ratio of (2:1), (1:1), and (1:2). The SEM images of all samples showed the agglomerate morphology between ZnO and graphite which affect the results of the battery performance test. The final result of the ZnO/Graphite anode can be considered a continuous anode material due to the stable cycle performance obtained in the range of 219.72–371.27 mAh/g with a decreased value of 40% after 55 cycles.