Reaktor
Volume 22 No. 3 December 2022

KINETICS OF ADSORPTION OF HEAVY METALS (IRON) FROM TEXTILE INDUSTRY WASTE USING CALCIUM CARBIDE RESIDUE AS ADSORBENT

Muhammad Arief Karim (Chemical Engineering Department, Faculty of Engineering, Muhammadiyah University Palembang)
Netty Herawati (Chemical Engineering Department, Faculty of Engineering, Muhammadiyah University Palembang)
Henny Juniar (Chemical Engineering Department, Faculty of Engineering, Muhammadiyah University Palembang)



Article Info

Publish Date
24 Jan 2023

Abstract

This research was conducted to study the efficiency of residual calcium carbide as an adsorbent using a batch process to remove iron (II) from textile industrial waste. In this study, the iron (II) content in textile industrial waste was synthetically made using . The effluent was characterized using a standard method (atomic absorption spectrometry), while the functional groups responsible for the Adsorption of iron to the surface of the calcium carbide residue were observed using SEM and Fourier Transform Infra-red (FTIR). The SEM findings revealed a highly porous morphology. FTIR revealed the presence of various functional groups (OH, CH, C=C, and C-C). Factors affecting Adsorption, eg, contact time, adsorbent dose, pH, and iron concentration, were also studied. The maximum iron (II) ion adsorption was observed to occur at pH 6. Kinetic studies showed a good correlation and best suited the pseudo-second-order kinetic model. Langmuir and Freundlich's isotherm model was used to describe the Adsorption of iron (II) on calcium carbide residues. The data obtained from the adsorption process most closely matched the Langmuir model with a correlation value of R^2 = 0.9959 and q_e=1.697 mg/g. with a pseudo-second-order kinetic model with a correlation coefficient value (R2), which is 0.9962 for an adsorbent mass of 7.5 g. The Adsorption of iron ions from textile wastewater synthesis solution using calcium carbide residues shows a physisorption mechanism.

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Journal Info

Abbrev

reaktor

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Control & Systems Engineering Energy Materials Science & Nanotechnology

Description

Reaktor invites contributions of original and novel fundamental research. Reaktor publishes scientific study/ research papers, industrial problem solving related to Chemical Engineering field as well as review papers. The journal presents paper dealing with the topic related to Chemical Engineering ...