International Journal of Advances in Applied Sciences
Vol 12, No 1: March 2023

Andisol and microcrystalline cellulose from Typha angustifolia for auramine O adsorption

Pranoto Pranoto (Sebelas Maret University)
Venty Suryanti (Sebelas Maret University)
Robi'atul Adawiyah (Sebelas Maret University)



Article Info

Publish Date
01 Mar 2023

Abstract

Andisol has a large surface area, is mesoporous, and contains the active groups' silanol (Si-OH) and aluminol (Al-OH). Besides andisol, cellulose is a good adsorbent, because microcrystalline cellulose has an active hydroxyl group (OH). The number of active adsorbent groups can be enhanced by chemically modifying the surface area (increment), or adding other materials. These modifications included alkaline modified-andisol with the addition of NaOH to increase pore size, cellulose hydrolysis with HCl to increase surface area, and andisol modification with the inclusion of other materials, mainly cellulose, to increase surface area. After the adsorption process is complete, the adsorption capacity of andisol-microcrystalline cellulose (AMS) to auramine O (AO) is known. As an adsorbent for AO, the surface area of BET andisol is 25.92 m2/g and the pore diameter is 14.40 nm, while the surface area of microcrystalline cellulose and AMS adsorbent are 26.60 m2/g and 18.60 m2/g, respectively. The maximum AO adsorption conditions by AMS were at pH 7, optimum at a contact time of 5 minutes, and maximum at a concentration of 40 mg/L with an adsorbent ratio of 1:1. The adsorption kinetics and isotherm more closely followed the pseudo second-order and Langmuir isotherm with an adsorption capacity of 5.24 mg/g.

Copyrights © 2023






Journal Info

Abbrev

IJAAS

Publisher

Subject

Earth & Planetary Sciences Environmental Science Materials Science & Nanotechnology Mathematics Physics

Description

International Journal of Advances in Applied Sciences (IJAAS) is a peer-reviewed and open access journal dedicated to publish significant research findings in the field of applied and theoretical sciences. The journal is designed to serve researchers, developers, professionals, graduate students and ...