ADSORPTION CHARACTERISTIC OF IRON ONTO POLY[EUGENOL-CO-(DIVINYL BENZENE)] FROM AQUEOUS SOLUTION

Fitrilia Silvianti (Department of Rubber and Plastic Processing Technology, Politeknik ATK Yogyakarta, Jl. Ringroad Selatan, Glugo, Panggungharjo, Sewon, Bantul, Yogyakarta 55188)
Dwi Siswanta (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO. Box BLS 21, Yogyakarta 55281)
Nurul Hidayat Aprilita (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO. Box BLS 21, Yogyakarta 55281)
Agung Abadi Kiswandono (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Lampung, Jl. Soemantri Brojonegoro No.1 Rajabasa Bandarlampung)

Jurnal Natural
Volume 17, Number 2, September 2017

A study on the adsorption characteristic of Iron onto Poly[eugenol-co-(divinyl benzene)] (EDVB) from aqueous solution has been conducted. EDVB was produced and characterized by using FTIR spectroscopy. The adsorption was studied by a batch method by considering the factors affecting the adsorption such as initial metal ion concentration, adsorption selectivity, and mechanism of adsorption using a sequential desorption method. The adsorption of Iron onto EDVB followed a pseudo-2 order kinetics model with the rate constant of 0,144 L2 mmol-1 min-1. The adsorption isotherm was studied with Tempkin, Langmuir and Freundlich models. The adsorption capacity (Qmax) obtained by Langmuir isotherms was 250mg.L-1 while the equilibrium value was 0.8 Lmg-1. A competitive adsorption study showed that EDVB is adsorbed selectively towards Iron rather than Chromium, Coppers and Cadmium ions. 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