Journal of Global Pharma Technology
Volume 11 Issue 05.

Mesoporous Silica and Zno@Sio2 as Adsorbents for Crystal Violet Dye Removal from Aqueous Solutions

Sameer H. Kareem (Unknown)



Article Info

Publish Date
16 Nov 2016

Abstract

Sol-gel method was used to prepare two samples of mesoporous Silica (mSiO2) and zinc oxide- mesoporous silica (ZnO@mSiO2) in the presence of HydroxycetylHydroxy ethyl Diamonium Chloride (dehyquart) surfactant as template. The two adsorbents prepared were characterized by nitrogen adsorption-desorption, XRD and AFM techniques. The results show that the mSiO2 sample has a mesopores in the range 2- 8 nm with a high degree of ordering of the porous structure, while Zn@SiO2 sample has pore distribution in the range 2-50 nm. The adsorption ability of the two adsorbents to removal of Crystal Violet (CV) dye from aqueous systems has been studied using a batch experiments method to measure the adsorption as a function of contact time and adsorbent dose at the temperature 293 K. Adsorption isotherms were fitted with the Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich models and the results show a best fitted for the two adsorbents, and the adsorption processes were physical adsorption type. The kinetic data were analyzed and found to match well with pseudo-second order kinetic model.Keywords: Mesoporous silica, Crystal Violet, Zn@SiO2, Adsorption isotherm.

Copyrights © 2016






Journal Info

Abbrev

jgpt

Publisher

Subject

Medicine & Pharmacology

Description

ournal of Global Pharma Technology is a monthly, open access, Peer review journal of Pharmacy published by JGPT Journal publishes peer-reviewed original research papers, case reports and systematic reviews. The journal allows free access to its contents, which is likely to attract more readers and ...