JURNAL KIMIA SAINS DAN APLIKASI
Vol 26, No 4 (2023): Volume 26 Issue 4 Year 2023

The Correlation between Dye absorption Wavelength and Illumination Wavelength on DSSC Performance

Hery Suyanto (Physics Department, Faculty of Mathematics and Natural Sciences, Udayana University, Jl. Kampus Bukit Jimbaran, Badung- Bali 80362|Udayana University|Indonesia)
Manuntun Manurung (Chemistry Department, Faculty of Mathematics and Natural Sciences, Udayana University, Jl. Kampus Bukit Jimbaran, Badung- Bali 80362|Udayana University|Indonesia)
I Putu Tedy Indrayana (Physics Department, Faculty of Mathematics and Natural Sciences, Udayana University, Jl. Kampus Bukit Jimbaran, Badung- Bali 80362|Udayana University|Indonesia)
Fiar Tri Santika (Physics Department, Faculty of Mathematics and Natural Sciences, Udayana University, Jl. Kampus Bukit Jimbaran, Badung- Bali 80362|Udayana University|Indonesia)



Article Info

Publish Date
30 Jun 2023

Abstract

This study examines the effect of the wavelength of light illuminated on DSSC on the absorption wavelength and gap dye energy. The dye used was sea lettuce anthocyanin from Sanur Beach, Bali. As much as 20 grams of dried sea lettuce powder was dissolved in 80 mL of 96% ethanol and 6% HCl. After 24 hours of immersion, it was filtered with Whatman 41 paper. The filtrate was characterized using a UV-Vis-NIR spectrophotometer so that the absorption wavelengths of the anthocyanin dye were 272.5 nm, 417 nm, and 653.5 nm. The gap energy was calculated using the Tauc Plot method, and the result was 2.826 eV. The dye was applied to make DSSC using the sandwich method, which was then irradiated with white, red, and purple LEDs with respective wavelengths of 400–700 nm (with peaks at 439.67 nm and 550.29 nm), 629.04 nm and 425.38 nm and variations in intensity values, namely 1000 lux, 2000 lux, and 3000 lux. Illumination using purple LEDs produces the maximum current and highest efficiency compared to white and red, namely 1.33 mA, 1.57 mA, and 1.83 mA for 1000 lux, 2000 lux, and 3000 lux, respectively, and the efficiency is 0.0039 for 1000 lux. The purple color has a wavelength close to and intersects with the absorbance wavelength of the dye and has energy (2.918 eV) greater than the gap energy of the sea lettuce dye.

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Journal Info

Abbrev

ksa

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Engineering

Description

urnal Kimia Sains dan Aplikasi (p-ISSN: 1410-8917) and e-ISSN: 2597-9914) is published by Department of Chemistry, Diponegoro University. This journal is published four times per year and publishes research, review and short communication in field of ...