Molekul: Jurnal Ilmiah Kimia
Vol 17 No 1 (2022)

Selective Colorimetric Detection of Mercury(II) using Silver Nanoparticles-Chitosan

Monica Avissa (Universitas Negeri Semarang)
Mohammad Alauhdin (Department of Chemistry Universitas Negeri Semarang)



Article Info

Publish Date
13 Mar 2022

Abstract

Contamination of the environment by hazardous metal ions has been a major environmental issue for the past several decades. Among several hazardous metals, mercury ion (Hg(II)) is of particular concern as its compounds are extremely toxic. Hence, developing detection methods for traces of Hg(II) ions in aquatic systems is critical for mercury pollution mitigation. One method that can be used to monitor Hg(II) in aquatic systems is colorimetry-based method which is simple, rapid, and low-cost, yet selective and sensitive. The method can be conducted by applying the Localized Surface Plasmon Resonance phenomenon of metal nanoparticles, such as silver nanoparticles. There are non-Hg(II) ions in the aquatic environment that can interfere the measurements. Thus, a selective method is needed to obtain a valid measurement result. Here, we introduced silver nanoparticles-chitosan (AgNPs-Ch) synthesized by chemical reduction as a selective probe of Hg(II) in an aqueous solution. The AgNPs-Ch was synthesized from silver nitrate at 80°C using trisodium citrate and chitosan as reducing agent and stabilizer, respectively. The synthesized nanoparticles were spherical with an average size below 15.0 nm. Moreover, the AgNPs-Ch was selective for Hg(II) with a linearity of 0.9556 in the concentration range of 1 - 5 ppm and was able to detect the ion down to 1.33 ppm.

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Journal Info

Abbrev

jm

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemistry Materials Science & Nanotechnology

Description

The MOLEKUL is dedicated to fostering advancements in all branches of chemistry and its diverse sub-disciplines. It aims to publish high-quality research encompassing a wide range of topics, including but not limited to Pharmaceutical Chemistry, Biological Activities of Synthetic Drugs, ...