Natural B
Vol 3, No 2 (2015)

Effect of Sintering Temperature on Percentage of Tetragonal And Rhombohedral On Comparison of Zr / Ti (60/40)

Tamam Abimanyu (Jurusan Kimia Fakultas MIPA Universitas Brawijaya Jalan Veteran Malang 65145)
Rachmat Triandi (Jurusan Kimia Fakultas MIPA Universitas Brawijaya Jalan Veteran Malang 65145)
Masruroh Masruroh (Jurusan Fisika Fakultas MIPA Universitas Brawijaya Jalan Veteran Malang 65145)



Article Info

Publish Date
10 Nov 2015

Abstract

The synthesis of lead zirconate titanate (PZT) with ratio Zr:Ti of 60:40 have been conducted by sol gel method. The precursor of PZT were prepered from zirconium(IV) nitrate pentahydrate, titanium(IV) butoxide, lead(II) acetate trihydrate and 2-methoxyethanol and acetylaceton as a stabilizer solution. The PZT films deposited on Si substrate by spin coating method, then it was sintered at different temperature of 500°C, 600°C and 700°C. The crystal structure and composition of PZT films were observed by X-ray Diffraction (XRD) and Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDX). The XRD results show the crystal orientation of PZT (100), (101), (110), (111), (002)T, (200)R, (200)T, (201) and (210), means that all PZT films are polycrystalline. Moreover, the orientation of (110) as temperature sintered of 600°C show the highes intensity than other temperature. The EDX results show mole fraction of Zr and Ti decrease compound with iniatial precursor. On the other hand, the mole fraction of O increase, which result in the existence of ZrO2 and TiO2 crystal. 

Copyrights © 2015






Journal Info

Abbrev

NATURAL B

Publisher

Subject

Environmental Science

Description

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