Helium: Journal of Science and Applied Chemistry
Vol 1, No 2 (2021): Helium: Journal of Science and Applied Chemistry

Urea Core Coating with Crosslinked Hydrophilic Polymers for Controlled Release Fertilizer Application

Sujono Sujono (Integrated Laboratory)
Zainal A. Masud (Integrated Laboratory)



Article Info

Publish Date
31 Dec 2021

Abstract

Controlled release fertilizer (CRF) can be made by coating the fertilizer core with a polymer layer. The simultaneous coating reaction of the polymerization needs to be controlled in the reactor. A controlled reactor system was developed for the polymerization of granular fertilizer coating using integrated electronic control of the 8-bit ATTiny 2313 AVR microcontroller chip. Urea granule fertilizer is coated with hydrophilic polymer polyacrylamide and crosslinked polyacrylate with N,N'-methylene-bis acrylamide (MBA). The reaction was initiated by benzoyl peroxide (BPO) at 61 oC. The coating was successfully formed in 45 minutes reaction. The coating process in the control reactor was more effective than without control, thereby reducing the deposition of polymer deposits that did not coat the fertilizer. The characterization of the fertilizer coating layer based on infrared spectroscopy (FTIR) showed that polymerization synthesis had occurred based on the presence of C=C bonds. The IR spectrum showed a reduced absorption of the C=C stretching vibration medium in the acrylamide monomer compared with the polymer (crosslinked polyacrylamide), namely the wavenumbers of 1614 cm-1 in acrylamide and 1601 cm-1 in polyacrylamide spectrum. Similarly, the loss of C=C absorption in the crosslinked polyacrylate spectrum but appeared in the acrylic monomer spectrum at 1636 cm-1 wave. This group is reduced or lost after polymerization due to an addition reaction.

Copyrights © 2021






Journal Info

Abbrev

he_jsac

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Energy Materials Science & Nanotechnology

Description

Welcome to Helium: Journal of Science and Applied Chemistry. Helium: Journal of Science and Applied Chemistry is a journal that publishes scientific papers in the field of chemistry. This Journal, run by Chemistry Study Program, Universitas Pakuan, Bogor. The Journal provides opportunities for ...