JURNAL KIMIA SAINS DAN APLIKASI
Vol 26, No 7 (2023): Volume 26 Issue 7 Year 2023

Corrosion Inhibition Behavior of DL-Methionine and L-Tryptophan on Carbon Steel

Achmad Rochliadi (Research Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Bandung|Institut Teknologi Bandung|Indonesia)
Aep Patah (Research Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Bandung|Institut Teknologi Bandung|Indonesia)
Claudia Claudia (Research Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Bandung|Institut Teknologi Bandung|Indonesia)
Dadang Ramadhan (Research Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Bandung|Institut Teknologi Bandung|Indonesia)



Article Info

Publish Date
05 Nov 2023

Abstract

The cost-effective, efficient, and environmentally friendly corrosion inhibitors have become increasingly significant within the oil and gas sector. Consequently, this research was conducted to evaluate the corrosion inhibition behavior of the amino acids DL-Met and L-Tryp on carbon steel in acidic (0.05 M HCl), alkaline (0.05 M NH4OH), and neutral (3% NaCl) environments. This study used Electrochemical Impedance Spectroscopy (EIS) and Potentiodynamic Polarization (PDP) to assess the performance of amino acids as corrosion inhibitors. The EIS and PDP measurements revealed that DL-Met and L-Tryp exhibited corrosion inhibition effects exclusively in acidic conditions. In this environment, DL-Met demonstrated a corrosion inhibition efficiency (η) of 49.7% at a concentration of 525 ppm, while L-Tryp reached an efficiency of 87.08% at a concentration of 25 ppm. Under the same conditions, DL-Met reduced the corrosion rate from 10 mm/year to 4.468 mm/year, and L-Tryp reduced it from 10.95 mm/year to 5.003 mm/year. However, the corrosion inhibition activity of DL-Met and L-Tryp in neutral and alkaline conditions did not yield positive results according to EIS measurements. In neutral conditions, 100 ppm DL-Met exhibited -22.46% inhibitory activity. Meanwhile, in alkaline conditions, 150 ppm DL-Met and 5 ppm L-Tryp exhibited inhibition efficiencies of -72.39% and -81.9%, respectively. This research aims to provide the oil and gas industry with a natural-based corrosion inhibitor alternative, offering a solution to corrosion-related challenges in acidic conditions.

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Journal Info

Abbrev

ksa

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Engineering

Description

urnal Kimia Sains dan Aplikasi (p-ISSN: 1410-8917) and e-ISSN: 2597-9914) is published by Department of Chemistry, Diponegoro University. This journal is published four times per year and publishes research, review and short communication in field of ...