Bulletin of Chemical Reaction Engineering & Catalysis
2021: BCREC Volume 16 Issue 1 Year 2021 (March 2021)

Physical-chemical Characterization of Nano-Zinc Oxide/Activated Carbon Composite for Phenol Removal from Aqueous Solution

Allwar Allwar (Department of Chemistry, Faculty Mathematics and Natural Sciences, Universitas Islam Indonesia, Yogyakarta, 55584)
Asih Setyani (Department of Chemistry, Faculty Mathematics and Natural Sciences, Universitas Islam Indonesia, Yogyakarta, 55584)
Ulul Sugesti (Department of Chemistry, Faculty Mathematics and Natural Sciences, Universitas Islam Indonesia, Yogyakarta, 55584)
Khusna Afifah Fauzani (Department of Chemistry, Faculty Mathematics and Natural Sciences, Universitas Islam Indonesia, Yogyakarta, 55584)



Article Info

Publish Date
31 Mar 2021

Abstract

Oil palm shell was used as a precursor for preparation of activated carbon using different chemical activations (potassium hydroxide (KOH), zinc chloride (ZNCl2), and phosphoric acid (H3PO4)). Each activated carbons (AC) was mixed with nano-zinc oxide to form a composite. From the gas sorption analyzer, it is showed that nitrogen adsorption isotherms show Type II for ZnO/AC-KOH and ZnO/AC-ZnCl2 corresponding to the micro- and mesoporous structures, respectively. However, the nitrogen adsorption isotherm of ZnO/AC-H3PO4 exhibits the Type I with predominantly microporous structures. The SEM micrographs produced unsmooth surface and different pore sizes. The XRD patterns at 2θ of 25.06° and 26.75° were come from amorphous activated carbon. The peak intensity of ZnO was weak due to low concentration of zinc precursor. However, the ZnO of ZnO/AC-ZnCl2 showed strongly peak intensity. The effectiveness of the composites was examined for phenol removal determined by UV-Vis Spectrophotometer method. The equilibrium adsorption follows the Langmuir and Freundlich models according to the best correlation coefficient (R2). The kinetic model was only obtained for the pseudo-second-order with the best linearity of the correlation coefficient (R2). The results of this study showed that the oil palm shell has a great potential for ZnO/AC with excellent adsorptive property. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 

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Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis, a reputable international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics, and chemical reaction engineering. Scientific articles dealing with the following topics in ...