Kinetic Study of Esterification of Acetic Acid with n-butanol and isobutanol Catalyzed by Ion Exchange Resin

Amrit Pal Toor (University Institute of Chemical Engineering & Technology, Panjab University, Chandigarh-160014)
Mamta Sharma (University Institute of Chemical Engineering & Technology, Panjab University, Chandigarh-160014)
Ghansyam Kumar (University Institute of Chemical Engineering & Technology, Panjab University, Chandigarh-160014)
R. K. Wanchoo (University Institute of Chemical Engineering & Technology, Panjab University, Chandigarh-160014)

Bulletin of Chemical Reaction Engineering & Catalysis
2011: BCREC Volume 6 Issue 1 Year 2011 (June 2011)

Esters are an important pharmaceutical intermediates and very useful perfumery agents. In this study the esterification of acetic acid with n-butanol and iso-butanol over an acidic cation exchange resin, Amberlyst 15 were carried out. The effects of certain parameters such as temperature, catalyst loading, initial molar ratio between reactants on the rate of reaction were studied. The experiments were conducted in a stirred batch reactor in the temperature range of 351.15 K to 366.15K.Variation of parameters on rate of reaction demonstrated that the reaction was intrinsically controlled.The activation energy for the esterification of acetic acid with n-butanol and iso butanol is found to be 28.45 k J/mol and 23.29 kJ/mol respectively. © 2011 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)