Application of La-ZSM-5 Coated Silicon Carbide Foam Catalyst for Toluene Methylation with Methanol

Debarpita Ghosal (Department of Chemical Engineering, Indian Institute of Technology Kharagpur)
Jayanta Kumar Basu (Department of Chemical Engineering, Indian Institute of Technology Kharagpur)
Sonali Sengupta (Department of Chemical Engineering, Indian Institute of Technology Kharagpur)

Bulletin of Chemical Reaction Engineering & Catalysis
2015: BCREC Volume 10 Issue 2 Year 2015 (August 2015)

The performance of toluene methylation reaction was studied on H-ZSM-5 catalyst modified with La, Ce and Nb at different percentage loading. It was found that 10% metal loading produced the best performance in the reaction in terms of toluene conversion. The catalyst was coated on silicon carbide foam support which showed better conversion than the pelleted catalyst. Again, among the treated and untreated H-ZSM-5, the La-ZSM-5 catalyst is chosen for the reaction for its highest selectivity towards xylene, the main product. All catalysts were characterized in terms of surface properties, SEM, XRD and NH3-TPD. Kinetic study was done on La-ZSM-5 catalyst with 10% loading. In this kineticstudy, Langmuir Hinshelwood kinetic model with surface reaction as rate controlling step was selected as the rate equation. The activation energy was found to be 47 kJ/mol. © 2015 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)