Bulletin of Chemical Reaction Engineering & Catalysis
2018: BCREC Volume 13 Issue 2 Year 2018 (August 2018)

Simple and Green Adipic Acid Synthesis from Cyclohexanone and/or Cyclohexanol Oxidation with Efficient (NH4)xHyMzPMo12O40 (M: Fe, Co, Ni) Catalysts

Sihem Mouanni (Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB), BP 32, El-Alia, 16111 Bab-Ezzouar, Alger)
Tassadit Mazari (Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB), BP 32, El-Alia, 16111 Bab-Ezzouar, Alger|Algeria Département de Chimie, Faculté des Sciences, Université Mouloud Mammeri )
Sihem Benadji (Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB), BP 32, El-Alia, 16111 Bab-Ezzouar, Alger)
Leila Dermeche (Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB), BP 32, El-Alia, 16111 Bab-Ezzouar, Alger|Algeria Département de Chimie, Faculté des Sciences, Université Mouloud Mammeri )
Catherine Marchal-Roch (ILV-UMR 8180 CNRS, Université de Versailles -St Quent -en-Yvelines, Bâtiment Lavoisier, 45 avenue des Etats-Unis, 78035 Versailles Cedex)
Cherifa Rabia (Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB), BP 32, El-Alia, 16111 Bab-Ezzouar, Alger)

Article Info

Publish Date
01 Aug 2018

Abstract

The oxidation of cyclohexanone and/or cyclohexanol to adipic acid (AA) was performed at 90 °C with a reaction time of 20 h, in the presence of H2O2 as oxidant and transition metal substituted ammonia polyoxometalates of formula, (NH4)xHyMzPMo12O40 (M: Fe, Co, or Ni,  and x = 2.5 or 2.28) as catalysts.  The catalytic results showed that the AA yield is sensitive to the transition metal nature and to the reaction conditions (sample weight and substrate amount). The (NH4)2.29H0.39Co0.16PMo12O40 was found to be the better catalytic system toward AA synthesis from cyclohexanone oxidation, with 40% of AA yield 

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Journal Info
Bulletin of Chemical Reaction Engineering & Catalysis
Website

Abbrev

bcrec

Publisher

Masyarakat Katalis Indonesia - Indonesian Catalyst Society

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis, a reputable international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics, and chemical reaction engineering. Scientific articles dealing with the following topics in ...