Bulletin of Chemical Reaction Engineering & Catalysis
2021: BCREC Volume 16 Issue 1 Year 2021 (March 2021)

The Influence of Metal Loading Amount on Ni/Mesoporous Silica Extracted from Lapindo Mud Templated by CTAB for Conversion of Waste Cooking Oil into Biofuel

Cahyarani Paramesti (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada)
Wega Trisunaryanti (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada)
Savitri Larasati (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada)
Nugroho Raka Santoso (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada)
Sri Sudiono (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada)
Triyono Triyono (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada)
Dyah Ayu Fatmawati (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada)



Article Info

Publish Date
31 Mar 2021

Abstract

The synthesis and characterization of Ni/mesoporous silica (Ni/MS) catalysts from Lapindo mud with various metal loading for the hydrocracking of waste cooking oil into biofuel has been conducted. The MS was synthesized by the hydrothermal method using CTAB as a template. The nickel-metal of 4, 6, and 8 wt% was loaded into the MS using salt precursors of Ni(NO3)2.6H2O via wet impregnation, produced the Ni(4)/MS, Ni(6)/MS, and Ni(8)/MS catalysts, respectively. The materials produced were then characterized by X-ray Powder Diffraction (XRD), Fourier-Transform Infrared Spectroscopy (FT-IR), and Surface Area Analyzer (SAA), and Absorption Atomic Spectrophotometry (AAS). The catalytic activity test was carried out for hydrocracking of waste cooking oil and the resulted liquid product was analyzed by Gas Chromatography-Mass Spectrometry (GC-MS). The results showed that the specific surface area of Ni(4)/MS, Ni(6)/MS, and Ni(8)/MS catalysts are 63.08, 91.45, and 120.45 m2/g, respectively. The liquid products of the hydrocracking using Ni(4)/MS, Ni(6)/MS, and Ni(8)/MS catalysts were 80.57, 74.63, and 75.77 wt%, where the total biofuel produced was 55.46, 50.93, and 54.05 wt%, respectively. Based on these results, Ni(4)/MS material was successfully used as the most potent catalyst in the hydrocracking of waste cooking oil into the biofuel. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 

Copyrights © 2021






Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis, a reputable international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics, and chemical reaction engineering. Scientific articles dealing with the following topics in ...