Bulletin of Chemical Reaction Engineering & Catalysis
2015: BCREC Volume 10 Issue 2 Year 2015 (August 2015)

Vulcanization Kinetics and Mechanical Properties of Ethylene Propylene Diene Monomer Thermal Insulation

Mohamad Irfan Fathurrohman (Indonesian Rubber Research Institute, Jl. Salak No. 1, Bogor16151)
Dadi Rusadi Maspanger (Indonesian Rubber Research Institute, Jl. Salak No. 1, Bogor16151)
Sutrisno Sutrisno (Rocket Technology Center, National Institute of Aeronautics and Space, Jl. Raya LAPAN No. 2, Mekarsari, Rumpin, Bogor 16350)



Article Info

Publish Date
30 Aug 2015

Abstract

The vulcanization kinetics of Ethylene-propylene diene monomer (EPDM) rubber thermal insulation was studied by using rheometer under isothermal condition at different temperatures. The rheometry analysis was used to determining the cure kinetic parameters and predicting the cure time of EPDM thermal insulation. The experimental results revealed that the curing curves of EPDM thermal insulation were marching and the optimum curing time decreased with increasing the temperature. The kinetic parameters were determined from the autocatalytic model showed close fitting with the experimental results, indicating suitability of autocatalytic model in characterizing the cure kinetics. The activation energy was determined from the autocatalytic model is 46.3661 kJ mol-1. The cure time were predicted from autocatalytic model and the obtained kinetic parameter by using the relationship among degree of conversion, cure temperature, and cure time. The predictions of cure time provide information for the actual curing characteristic of EPDM thermal insulation. The mechanical properties of EPDM thermal insulation with different vulcanization temperatures showed the same hardness, tensile strength and modulus at 300%, except at temperature 70 °C, while the elongation at breaking point decreased with increasing temperature of vulcanization. © 2015 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)

Copyrights © 2015






Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis, a reputable international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics, and chemical reaction engineering. Scientific articles dealing with the following topics in ...