JFA (Jurnal Fisika dan Aplikasinya)
Vol 6, No 1 (2010)

Optical Activity of an Asymmetric Substance

Frida Ulfah Ermawati (Universitas Negeri Surabaya)



Article Info

Publish Date
13 Jan 2010

Abstract

This paper reported the investigation on the property of optical activity from three different isomers of L-, Dand DL--alanine (CH3CHNH2CO2H), a proposed radiation dosimetric material. The aim was to confirm the impact of attachment of -carbon atom of the systems to the four different groups, that is, the -carbon or methyl group, H-group, CO2H-group and NH2-group, to their response to any incoming plane-polarized light. Optical activity of a substance is a measure of the ability of a substance to rotate a plane of polarization, if solution of the substance is placed in the path of plane-polarized light. A polarimeter of Perkin-Elmer Model 141 with a Sodium lamp of 584-nm wavelength (D-line) and equipped with a digital counter was occupied in this work to measure the number of degrees of rotation of plane-polarized light at room temperature due to 8.3% concentration of each L-, D- and DL--alanine solutions. It was obtained that molecules of L-isomer rotate the counter of the polarimeter clockwise, from the observer’s point a view. While the molecules of D-isomer rotate the counter anti clockwise, at the similar amount of rotation. These results confirm the asymmetric structure belong to the -alanine system. Molecules of DL-isomer, however, do not rotate the counter at all. The existence of similar number of the D- and L-molecules in the DL-solution is the cause.

Copyrights © 2010






Journal Info

Abbrev

jfa

Publisher

Subject

Physics

Description

JFA (Jurnal Fisika dan Aplikasinya, Abbreviation: J.Fis. dan Apl.) hanya menerbitkan artikel penelitian asli serta mengulas artikel tentang topik seputar bidang fisika (fisika teori, material, optik, instrumentasi, geofisika) dan aplikasinya. Naskah yang dikirimkan ke JFA belum pernah diterbitkan ...