World Chemical Engineering Journal
VOLUME 7 NO.1 JUNE 2023

STUDY OF REACTION KINETICS ON BIODIESEL PRODUCTION USING IN SITU METHOD WITHOUT CATALYST

Naulina, Rosada Yulianti (Institut Teknologi dan Sains Nahdlatul Ulama Pasuruan)
Hendratama, Handik (Institut Teknologi dan Sains Nahdlatul Ulama Pasuruan)
Nury, Dennis Farina (Institut Teknologi Sumatera)
Zullaikah, Siti (Institut Teknologi Sepuluh Nopember SURABAYA)



Article Info

Publish Date
30 Jun 2023

Abstract

Biodiesel from rice bran using an uncatalyzed in-situ transesterification method in subcritical ethanol - water has been investigated. This method is known to be economical because the experimental steps are reduced and environmentally friendly because we do not use a catalyst. In this experiment, CO2 was used as a compressed gas and ethyl acetate as a co-solvent to increase yield. This reactor is equipped with a stirrer that uses a magnetic stirrer. Rice bran, a mixture of water, ethanol and ethyl acetate in a mole ratio of 1:10:9:2 is fed into the reactor, then injecting CO2 gas to increase the pressure and to ensure the reaction takes place under subcritical conditions under operating pressure of 80 bar.Temperature (120 - 200ᵒC) and reaction time (1 - 4 hours) were investigated to increase biodiesel. The highest yield of FAEE composition at 200ᵒC for 3 hours was 91.264% with the results of calculating the kinetics of the transesterification reaction, the values of k1 and k2 were 0.349.10-3 and 0.0045 mL3.mmol-3.min-1. Meanwhile, in the esterification reaction, the values for k1 and k2 were 0.0194 and 0.0579 mL3.mmol-3.min-1.

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Journal Info

Abbrev

WCEJ

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering

Description

WCEJ publishes original papers and reviewed papers on the fundamental, theoretical as well as applications of Chemical Engineering. WCEJ is published two times a year. This journal covering some aspects of chemical engineering, which are environmental chemical engineering, chemical reaction ...