JOURNAL OF CHEMICAL NATURAL RESOURCES (JCNaR)
Vol. 6 No. 1 (2024): Journal of Chemical Natural Resources

Effect of Chitosan Addition on Porosity of Rice Husk Calcium Silicate Used for Free Fatty Acid Adsorbent from Palm Oil

Lumban Raja, Saur (Unknown)
Butarbutar, Olwin (Unknown)



Article Info

Publish Date
21 May 2024

Abstract

Studies have been done on developing calcium silicate pores derived from rice husk with and without including chitosan as a template. The chitosan solution was supplemented with sodium silicate derived from rice husk, and then CaCl2 was added. The calcium silicate was calcinated at 900ºC for 4 h. The calcium silicate obtained was characterized using X-ray diffraction (XRD), fourier transform infrared (FT-IR), and Brunauer-Emmett-Teller (BET)  analysis. The XRD analysis showed the presence of diffraction peaks corresponding to Wollastonite (CaSiO3) crystals, Wollastonite 2m (CaSiO3), Alite (Ca3SiO5), and larnite (Ca2SiO4). Next, the FT-IR spectrum exhibits Si-O-Si, Si-O-Ca, and Si-OH functional groups, suggesting the presence of calcium silicate material. The BET study of calcium silicate using chitosan templates revealed a pore size of 3.88 nm, a pore volume of 0.1577 cc/g, and a surface area of 81.1519 m2/g. The BET analysis results obtained differed from those of the BET analysis of calcium silicate conducted without using chitosan templates, which were 2.06 nm, 0.069 cc/g, and 13.531 m2/g, respectively. The developed mesoporous calcium silicate was employed as an adsorbent to decrease the concentrations of free fatty acids in palm oil. The acid-base titration method is used to evaluate quantities of free fatty acids. The results obtained from the computation of free fatty acid levels indicate a decline in the concentration of free fatty acids in palm oil. The concentration of free fatty acids derived from palm oil was 1.23%. Therefore, mesoporous calcium silicate-free fatty acids at a concentration of 1.06% resulted in an 86.1% reduction.

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Journal Info

Abbrev

JCNaR

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemistry Materials Science & Nanotechnology

Description

Journal of Chemical Natural Resources (JCNaR) is a peer-reviewed biannual journal (February and August) published by TALENTA as an open access journal. The aim of the journal is to provide a medium to exchange ideas and information related to research and knowledge in disciplines of organic ...