Bulletin of Chemical Reaction Engineering & Catalysis
2016: BCREC Volume 11 Issue 2 Year 2016 (August 2016)

Fish Bone-Catalyzed Methanolysis of Waste Cooking Oil

Sarina Sulaiman (Department of Biotechnology Engineering, Faculty of Engineering, International Islamic University of Malaysia, Kuala Lumpur)
M.H.M. Amin (Department of Biotechnology Engineering, Faculty of Engineering, International Islamic University of Malaysia, Kuala Lumpur)



Article Info

Publish Date
20 Aug 2016

Abstract

The use of cheaper alternative such as waste cooking oil as substitute to vegetable oil can reduce the overall production cost of biodiesel. This research focuses on the investigation of the kinetic of waste cooking oil methanolysis using heterogeneous waste catalyst. Fish bone waste was used as the catalyst for the methanolysis of waste cooking oil. The kinetic data obtained from this study can be used to optimize the process of biodiesel production. The effects of temperature and catalyst amount were varied between 50- 65 °C and 4-10 wt % respectively. The kinetic of transesterification of waste oil, the reaction rate constant (k) and activation energy (EA) at 55, 65 and 65 °C were determined. The highest yield of biodiesel, 86 % were achieved at 6 wt% of catalyst amount, mixing of 300 rpm, methanol to oil ratio of 18:1 and reaction temperature of 65 °C. The activation energy (Ea) was 34.12 kJ/mol. This study also proves that transesterification process is not affected by the internal mass transfer due to the Thiele modulus value between 0-1.69. 

Copyrights © 2016






Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis (e-ISSN: 1978-2993), an international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics studies, and chemical reaction ...