Science and Technology Indonesia
Vol. 2 No. 1 (2017): January

Bentonite intercalated organometallic complex as adsorbent of procion red

Lora Vitanesa (Unknown)
Radja Nardo Purba (Unknown)
Aldes Lesbani (Unknown)
Muhammad Said (Unknown)



Article Info

Publish Date
21 Jun 2017

Abstract

Insertion of bentonite with organometallic compounds [Cr3O(OOCH)6(H2O)3 (NO3)]as adsorbent of procion red with comparison weight ratio of bentonite: organometallic compounds [Cr3O(OOCH)6(H2O)3 (NO3)] i.e.: (2.5:1), (1:1), (1:2) and (1:3) has been done. The results of insertion bentonite were characterized using FT-IR spectrophotometer, XRD, and XRF. Furthermore, the product of optimum insertion was used as an adsorbent of procion red. The spectrogram from FT-IR shows the process of insertion was not optimum for every weight ratio. Characterization using XRD showed the optimum insertion process ratio (1:2) and (1:3) was indicated the presence of diffraction appearing at 2θ region by a shift in the diffraction angles 5.00 and 39o from the original activated bentonite of 20.8o. Characterization using XRF analysis in the ratio (1:3) shows percentage of metal oxide Cr2O3 increase to 82.28%, so at the ratio of 1:3, the process insertion of organometallic compounds into the bentonite has stated success base on its highest percentage. The adsorption process of insertion bentonite organometallic compounds [Cr3O(OOCH)6(H2O)3 (NO3)] ratio (1: 3) shows the magnitude of the rate of adsorption (k) at 0.004 min-1, the adsorption capacity (b), the largest at a temperature of 70oC at 72.99 mol/g, the largest adsorption energy (ΔG) at a temperature of 60oC i.e. 17.05 kJ / mol, the largest enthalpy (ΔH) is 105720.8 kJ/mol, entropy (ΔS) 315 kJ/mol and pH 11 has the biggest value of procion red adsorped, i.e. 33.38 mg/L. Keywords: Bentonite, Organometallic compound [Cr3O(OOCH)6(H2O)3(NO3)].Adsorption, Procion Red

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Journal Info

Abbrev

JSTI

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Environmental Science Materials Science & Nanotechnology Physics

Description

An international Peer-review journal in the field of science and technology published by The Indonesian Science and Technology Society. Science and Technology Indonesia is a member of Crossref with DOI prefix number: 10.26554/sti. Science and Technology Indonesia publishes quarterly (January, April, ...