JURNAL KIMIA SAINS DAN APLIKASI
Vol 28, No 6 (2025): Volume 28 Issue 6 Year 2025

Synthesis and Characterization of Nickel(II) Imprinted Polymers as a Selective Adsorbent for Nickel(II) Ions

Kartika, Siska Ela (Unknown)
Hariyanto, Putri Septiani (Unknown)
Madjid, Armeida D. R. (Unknown)
Siboro, Sonita Afrita Purba (Unknown)
Sujarwadi, Roni (Unknown)



Article Info

Publish Date
05 Aug 2025

Abstract

The rapid expansion of nickel mining in Indonesia, driven by the growing demand for electric vehicle batteries, has raised concerns about the environmental and health impacts of nickel pollution. This study presents the synthesis and characterization of a highly selective adsorbent, Nickel(II) Imprinted Polymer (Ni(II)-IPs), for the monitoring and removal of Ni(II) ions. Ni(II)-IPs were synthesized using precipitation polymerization by imprinting the Ni(II)-8-hydroxyquinoline complex into a polymer matrix through the polymerization of methacrylic acid and ethylene glycol dimethacrylate. Successful imprinting and subsequent leaching of Ni(II) ions using HNO3 were confirmed by FTIR, SEM, and EDX characterization. Adsorption studies revealed that Ni(II)-IPs exhibit a high adsorption capacity of 70.26 mg/g at pH 7 within a short contact time of 15 minutes. Moreover, Ni(II)-IPs demonstrated excellent selectivity towards Ni(II) ions in the presence of competing ions, with relative selectivity coefficients of 1.20, 1.24, and 1.31 for Ni(II)/Cu(II), Ni(II)/Co(II), and Ni(II)/Pb(II), respectively. These findings highlight the potential of Ni(II)-IPs as an efficient and selective adsorbent for monitoring and removing Ni(II) ions from complex aqueous matrices, thereby addressing growing concerns about nickel pollution in Indonesia and beyond.

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Journal Info

Abbrev

ksa

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Engineering

Description

urnal Kimia Sains dan Aplikasi (p-ISSN: 1410-8917) and e-ISSN: 2597-9914) is published by Department of Chemistry, Diponegoro University. This journal is published four times per year and publishes research, review and short communication in field of ...