Jurnal Bahan Alam Terbarukan
Vol 7, No 1 (2018): June 2018 [Nationally Accredited]

ESTERIFICATION OF NYAMPLUNG (Calophyllum inophyllum) OIL WITH IONIC LIQUID CATALYST OF BMIMHSO4 AND MICROWAVES-ASSISTED

Handayani, Prima Astuti (Unknown)
Wulansarie, Ria (Unknown)
Husaen, Paisal (Unknown)
Ulfayanti, Isna Mardya (Unknown)



Article Info

Publish Date
12 Mar 2018

Abstract

Nyamplung (Calophyllum inophyllum) oil contains high free fatty acid (FFA) that is 21.62%. Nyamplung oil can be utilized as raw material for biodiesel production. Microwave is a method of heating that is used intensively to speed up the production process. Ionic liquid has high catalytic activity, high selectivity, can be recycled and environmentally friendly. This study learned about the esterification of nyamplung oil with ionic liquid 1-Butyl-3-methylimidazolium hydrogen sulphate (BMIMHSO4) as catalyst and microwave-assisted. The purpose of this study is to obtain optimum condition of esterification process, with free fatty acid concentration (FFA) <2%. This study uses raw materials of nyamplung oil, methanol and BMIMHSO4 as catalyst. Equipment used in study was batch reactor equipped with temperature sensor with microwave heating system. The research variables studied were reaction temperature (50-70oC), molar ratio oil to methanol (1:30-1:60) and catalyst concentration (5-17.5%). The result of esterification reaction was analyzed by FFA (free fatty acid) content using titration analysis. The best free fatty acid (FFA) result was 1.92%, with molar ratio of oil to methanol was 1:40, catalyst concentration was 15% by weight and at 60oC for 120 min. The esterification of  nyamplung oil meets the criteria as biodiesel feedstock.

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Journal Info

Abbrev

jbat

Publisher

Subject

Materials Science & Nanotechnology

Description

This journal presents articles and information on research, development and applications in biomass conversion processes (thermo-chemical conversion; physico-chemical conversion and bio-chemical conversion) and equipment to produce fuels, power, heat, and value-added chemicals from biomass. A ...