Makara Journal of Science
Vol. 29, No. 1

Effect of Niobium Dopant on ZnO Thin Films Prepared via the Sol–gel Spin Coating Method

Eswar, Kevin Alvin (Unknown)
Rostan, Nur Fairuz (Unknown)
Mohamad, Maryam (Unknown)
Md Akhir, Rabiatuladawiyah (Unknown)
Rasmidi, Rosfayanti (Unknown)
Guliling, Muliyadi (Unknown)
Azhar, Najwa Ezira (Unknown)
Buniyamin, Irmaizatussyehdany (Unknown)
Malek, Mohd Firdaus (Unknown)
Mahmood, Mohamad Rusop (Unknown)
Suhaimi, Husairi Fadzilah (Unknown)
Abdullah, Saifollah (Unknown)



Article Info

Publish Date
10 Mar 2025

Abstract

Thin films of zinc oxide (ZnO) and niobium (Nb)-doped ZnO were deposited on a glass substrate using the sol–gel spin coating method. Diethanolamine, isopropyl alcohol, and zinc acetate served as the stabilizers, solvent, and starting ma-terial, respectively. Niobium pentachloride was employed as the dopant source. Energy-dispersive X-ray analysis con-firmed Nb incorporation. Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), and ultravio-let–visible spectroscopy (UV–Vis) analyses characterized the morphology, structure, and optics of the films, respective-ly. Both films, comprising nanoparticles, were visible in FESEM. Nb doping reduced the particle size from 44.2 nm to 35.8 nm. The XRD peaks at 31.23°, 33.48°, and 35.7° indicate the (100), (002), and (101) orientations, respectively. Nb-doped ZnO exhibited enhanced visible-range transmission in UV–Vis analysis. However, UV spectrum transmission significantly decreased. Nb doping reduced the optical bandgap of ZnO from 3.30 eV to 3.27 eV.

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Journal Info

Abbrev

publication:science

Publisher

Subject

Description

Makara Journal of Science publishes original research or theoretical papers, notes, and minireviews on new knowledge and research or research applications on current issues in basic sciences, namely: Material Sciences (including: physics, biology, and chemistry); Biochemistry, Genetics, and ...