Sorption Studies
Vol. 1 No. 2 (2025): Sorption Studies, December 2025

Modification of Calcium Oxide Catalyst Derived from Chicken Eggshell Waste with Magnesium Oxide to Enhance Biodiesel Synthesis from Crude Palm Oil

Hamidah, Fikriyah (Unknown)
Septaningsih, Dewi Anggraini (Unknown)
Fahri, Mirad (Unknown)
Basuki, Rahmat (Unknown)
Gunaryo (Unknown)
Subiakto, Amadea Kenyoning Hapsari (Unknown)
Nismarawati, Ardine Kusuma (Unknown)
Ningrum, Hanifa Setya (Unknown)
Fajry, Zaydan Al (Unknown)
Erwinda, Maura Agnes (Unknown)
Afandi, Achmad Kusyairi (Unknown)



Article Info

Publish Date
31 Dec 2025

Abstract

Biodiesel is a promising renewable energy source to replace conventional diesel fuel. This study aims to improve biodiesel production efficiency by utilizing a heterogeneous catalyst derived from chicken eggshell-based calcium oxide (CaO), modified with magnesium oxide (MgO). The catalyst was synthesized via co-precipitation and applied in both transesterification and interesterification reactions using crude palm oil (CPO) as feedstock. The optimum reaction was conducted at 65°C for 180 minutes with a 9:1 methyl acetate/methanol to oil molar ratio and 2.5 wt% catalyst loading. The modified CaO.MgO catalyst outperformed unmodified CaO, yielding 89.63% and 99.96% biodiesel via interesterification and transesterification, respectively. The catalyst characterization was performed using FTIR, XRD, and GC-MS, confirming the enhancement in basicity, crystallinity, and FAME content. This study demonstrates the potential of waste-derived catalysts in sustainable biodiesel production while addressing environmental waste issues.

Copyrights © 2025






Journal Info

Abbrev

ss

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Materials Science & Nanotechnology

Description

Sorption Studies (Sorpt. Stud.) is a peer-reviewed, open-access journal devoted to elucidating the fundamental aspects of chemistry and physics occurring at a wide range of adsorption and absorption and to disseminating this knowledge fast. The journal welcomes a broad spectrum of topics, including ...