International Journal of Acta Material
Vol. 2 No. 1 (2025): August 2025

Fabrication and Characterisation of Semi-Solid DSSCs Using Reduced Graphene Oxide (rGO) from Coal as a Filler in Polymer Gel Electrolytes

W. O. Sukmawati (Department of Physics, Faculty of Sciences and Mathematics, Halu Oleo University, Kendari, 93232, Indonesia.)
L. Ardan (Department of Physics, Faculty of Mathematics and Natural Sciences, Halu Oleo University, Kampus Hijau Bumi Tridharma, Kendari, Southeast, 93232, Indonesia)
I. Saleh (Department of Physics, Faculty of Mathematics and Natural Science, University of Halu Oleo, Kendari 93232, Indonesia)
L. Agusu (Department of Physics, Faculty of Mathematics and Natural Science, University of Halu Oleo, Kendari 93232, Indonesia)
I N. Sudiana (Department of Physics, Faculty of Mathematics and Natural Science, University of Halu Oleo, Kendari 93232, Indonesia)
I. Usman (Department of Physics, Faculty of Mathematics and Natural Science, University of Halu Oleo, Kendari 93232, Indonesia)



Article Info

Publish Date
28 Aug 2025

Abstract

In an effort to enhance the conductivity of TMSPMA-based polymer gel electrolytes (PGE), this study incorporated reduced graphene oxide (rGO) as a filler within the PGE matrix. The rGO was synthesized from sub-bituminous coal utilizing a modified Hummer method, while the PGE was formulated through a sol-gel process involving TMSPMA with varying proportions of rGO relative to the PGE. X-ray diffraction (XRD) measurements confirmed the presence of rGO, revealing a peak at a 2θ angle of 24.830° and a calculated crystalline size of 30.44 nm. Fourier-transform infrared spectroscopy (FTIR) characterization indicated that the identified functional groups were consistent with the molecular structure of TMSPMA. Impedance measurements conducted using an LCR meter demonstrated that the incorporation of rGO up to 0.04 g significantly enhanced the conductivity, achieving a value of 0.013 S/cm. Furthermore, photovoltaic performance testing of dye-sensitized solar cells (DSSC) indicated that the highest efficiency of 1.03% was attained with the PGE containing 0.04 g of rGO.

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Journal Info

Abbrev

journal

Publisher

Subject

Chemistry Materials Science & Nanotechnology Physics

Description

The International Journal of Acta Material (Int. J. Act. Mat) is a bulletin for publishing original and complete papers, short communications as well as review results which aim to disseminate study results (Theoretical or Experiment) to explore of the relationship between processes, structures and ...