TELKOMNIKA (Telecommunication Computing Electronics and Control)
Vol 20, No 6: December 2022

Surface coated red phosphors with silica nanoparticles and silica nanocomposites: performance modifications

Phuc Dang Huu (Industrial University of Ho Chi Minh City)
Tri-Vien Vu (Ton Duc Thang University)



Article Info

Publish Date
01 Dec 2022

Abstract

Surface coverings using nanomaterials of silica nanoparticles and poly (methyl methacrylate) – abbreviated “PMMA-silica nanomaterials” – are introduced to the Y2O2S:Eu3+ phosphor through four distinct approaches. The objective is to enhance Y2O2S:Eu3+ phosphorescence and prolonged sustainability. Using immerse-daubing along with sol-gel approach (Stober way), it is possible to have Y2O2S:Eu3+ phosphors covered with relatively-monodisperse nano-silica particles (5 nm). To create the silica nano-crystals employed in the coating process of phosphors, we carry out concurrently hydrolysis and condensation procedures to develop the formation and basic polymerization utilizing poly (1-vinyl-2-pyrrolidone). The surface coating layer for Y2O2S:Eu3+ spheres, which comprises polymethyl methacrylate (PMMA)-silica nanocomposites, can be formed in two ways: by combining silica nanogranules with methyl methacrylate (MMA) monomer as well as through subjecting MMA to tetraethyl orthosilicate (Si(OC₂H₅)₄) chemical compound. The latter approach demonstrated is considered the highest augmentation in phosphorescence and prolonged sustainability for Y2O2S:Eu3+ spheres. Specifically, when using the second approach to get PMMA-silica phosphor coating, Y2O2S:Eu3+ exhibited a 5-percent increase in the phosphorescent intensity, compared to untreated phosphors. Contrary to a drop in cathode phosphorescence (CP) output and a rising bombardment duration for exposed phosphor, the latter technique produces a practically constant CP energy with PMMA-silica nanocomposite covered phosphors.

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Journal Info

Abbrev

TELKOMNIKA

Publisher

Subject

Computer Science & IT

Description

Submitted papers are evaluated by anonymous referees by single blind peer review for contribution, originality, relevance, and presentation. The Editor shall inform you of the results of the review as soon as possible, hopefully in 10 weeks. Please notice that because of the great number of ...