ALCHEMY Jurnal Penelitian Kimia
Vol 13, No 2 (2017): September

SYNTHESIS AND CHARACTERIZATION OF CERAMIC METAL Ni-YSZ PREPARED FROM LOCAL ZIRCON SAND AT VARIOUS Ni:YSZ COMPOSITION

Karima Apriany (Research Group of Solid State Chemistry & Catalysis, Program Studi Kimia, Universitas Sebelas Maret, Jl. Ir. Sutami 36 A, Kentingan Surakarta 57126)
Fitria Rahmawati (Research Group of Solid State Chemistry & Catalysis, Program Studi Kimia, Universitas Sebelas Maret, Jl. Ir. Sutami 36 A, Kentingan Surakarta 57126)
Eddy Heraldy (Research Group of Solid State Chemistry & Catalysis, Program Studi Kimia, Universitas Sebelas Maret, Jl. Ir. Sutami 36 A, Kentingan Surakarta 57126)
Dani G Syarif (PTNBR Badan Tenaga Atom Nasional, Jl. Taman Sari, Bandung 40132)
Syoni Soepriyanto (Teknik Metalurgi, Fakultas Teknik Pertambangan dan Perminyakan, Institut Teknlogi Bandung, Jl. Ganesha 10, Bandung 40132)



Article Info

Publish Date
01 Sep 2017

Abstract

This research synthesized a cermet Ni-YSZ, in which the YSZ (yttria stabilized-zirconia) was synthesized from the local zircon sand, ZrSiO4, as a side product of tin mining plant in Bangka island, Indonesia. The synthesized YSZ in this research is zirconia, ZrO2 doped by 8 % mol of yttrium dioxide. The synthesis used solid state reaction method and the result was characterized its crystal structure and its cell parameters by XRD analysis equipped with Le Bail refinement, surface morphology analysis, and an impedance analysis to understand its ionic conductivity. The cermet Ni-YSZ was synthesized at a various composition of Ni:YSZ i.e., 20:80, 30:70, and 40:60 (b/b). The analysis shows that Ni-YSZ is in two phases of Ni and YSZ without any presence of a third phase. It indicates that there was no solid state reaction between Ni and YSZ during synthesis. In this Ni-YSZ cermet, the Ni phase in a cubic structure, and the YSZ is also in a cubic structure. Morphological study shows that the addition of Ni to YSZ allows the morphology to become more roughness with larger grain size. This research found that the Ni-YSZ 20:80 has highest ionic conductivity.

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Journal Info

Abbrev

alchemy

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Energy Environmental Science Materials Science & Nanotechnology

Description

ALCHEMY Jurnal Penelitian Kimia is a chemistry journal published by Sebelas Maret University, Surakarta. ALCHEMY Jurnal Penelitian Kimia publishes original research articles or review articles in organic chemistry, inorganic chemistry, analytical chemistry, physical chemistry, biochemistry, and ...