Indonesian Journal of Science and Technology
Vol 3, No 2 (2018): IJoST: VOLUME 3, ISSUE 2, September 2018

Limitation in Fabricating PSf/ZIF-8 Hollow Fiber Membrane for CO2/CH4 Separation

Nik Abdul Hadi Md Nordin (Chemical Engineering Department, Universiti Teknologi PETRONAS (UTP), 32610 Seri Iskandar, Perak, Malaysia)
Ahmad Fauzi Ismail (Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia (UTM), 81310 Skudai, Johor, Malaysia)
Surya Murali Racha (Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia (UTM), 81310 Skudai, Johor, Malaysia)
Ng Be Cheer (Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia (UTM), 81310 Skudai, Johor, Malaysia)
Muhammad Roil Bilad (Chemical Engineering Department, Universiti Teknologi PETRONAS (UTP), 32610 Seri Iskandar, Perak, Malaysia)
Zulfan Adi Putra (Chemical Engineering Department, Universiti Teknologi PETRONAS (UTP), 32610 Seri Iskandar, Perak, Malaysia)
Mohd Dzul Hakim Wirzal (Chemical Engineering Department, Universiti Teknologi PETRONAS (UTP), 32610 Seri Iskandar, Perak, Malaysia)



Article Info

Publish Date
30 Aug 2018

Abstract

Hollow fiber membrane configuration is way forward in membrane development since it possesses higher packing density and effective surface area per unit module compared to other configuration. Since majority of mixed matrix membrane (MMM) for gas separation reported focuses on flat sheet membrane development, this report aims to address the challenges faced in fabricating hollow fiber MMM. In this study, hollow fiber formulation is fabricated and their MMM using different types of fillers (virgin and modified ZIF-8) are prepared and used as a dispersed phase. The neat hollow fiber membrane shows good results with CO2 permeance of 104.39 GPU and CO2/CH4 selectivity of 29.28, in comparison with reported literature. Upon filler incorporation, the resulted MMMs appear to be diminished in both CO2 permeance and CO2/CH4 selectivity. While using modified ZIF-8, lesser deterioration was shown compared to pure ZIF-8, this phenomenon is likely to occur due to the changes in solution stability which causes notable changes in membrane morphology and performances.

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