Bulletin of Chemical Reaction Engineering & Catalysis
2018: BCREC Volume 13 Issue 3 Year 2018 (December 2018)

The Effect of Aluminum Source on Performance of Beta-Zeolite as a Support for Hydrocracking Catalyst

Mina Hadi (Catalysis Research Division, Research Institute of Petroleum Industry (RIPI), Tehran)
Hamid Reza Aghabozorg (Catalysis Research Division, Research Institute of Petroleum Industry (RIPI), Tehran)
Hamid Reza Bozorgzadeh (Catalysis Research Division, Research Institute of Petroleum Industry (RIPI), Tehran)
Mohammad Reza Ghasemi (Catalysis Research Division, Research Institute of Petroleum Industry (RIPI), Tehran)



Article Info

Publish Date
04 Dec 2018

Abstract

In this paper, three different kinds of aluminum sources (sodium aluminate, aluminum sulfate and aluminum isopropylate) were used for preparing of nano beta-zeolite. The as synthesized zeolites were mixed with the as prepared amorphous silica-alumina to produce the supports for hydrocracking catalyst. The prepared supports were used for preparation of NiMo/silica alumina-nano beta-zeolite by impregnation method. The influence of the aluminum source for preparation of beta-zeolite on the performance of the prepared catalysts has been studied. The samples were thoroughly characterized by X-Ray diffraction method (XRD), field emission-scanning electron microscopy (FE-SEM), N2 adsorption-desorption isotherms (BET), temperature programmed desorption (TPD) and temperature programmed reduction (TPR) methods. The catalysts performance was evaluated by vacuum gas oil (VGO) hydrocracking at 390 oC in a fixed bed reactor. The XRD patterns showed that the beta-zeolite samples obtained from the present methods were pure and highly crystalline and the crystal size of the prepared zeolites were in nanometer scale. Crystallite size of nano beta-zeolite synthesized by aluminum isopropylate [Al(iPrO)3] was smaller than those of prepared by the other aluminum sources. The catalyst containing this zeolite with higher surface area (231 m2/g) and more available acid sites (1.66 mmol NH3/g) possessed higher activity and selectivity to gas oil (71.9 %). 

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Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis (e-ISSN: 1978-2993), an international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics studies, and chemical reaction ...