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Seminar Nasional Teknik Kimia Kejuangan
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Prosiding Seminar Nasional Teknik Kimia Kejuangan adalah media online dari makalah yang telah diseminarkan pada acara Seminar Nasional Teknik Kimia “Kejuangan” (SNTKK). SNTKK merupakan agenda tahunan yang diselenggarakan oleh Program Studi Teknik Kimia FTI UPN ”Veteran” Yogyakarta. Seminar ini merupakan sarana komunikasi bagi para peneliti dari perguruan tinggi, institusi pendidikan, serta lembaga penelitian maupun industri, dalam mengembangkan teknologi kimia untuk pengolahan sumber daya alam Indonesia.
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Articles 85 Documents
Search results for , issue "2015: Prosiding SNTKK 2015" : 85 Documents clear
Aplikasi Bioleaching Dalam Pemisahan Logam dari Batuan Mineral Pyrite dengan Menggunakan Bakteri Thiobacillus ferooxidans dan Fungi Aspergillus niger Ronny Kurniawan
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2015: Prosiding SNTKK 2015
Publisher : Seminar Nasional Teknik Kimia Kejuangan

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Abstract

Pyrite (FeS2) is one of the types of sulphide minerals which are common in the nature. Many methods can be used to separate the metal content in pyrite, either chemical treatment, biological treatment, and physical treatment. This study generally aims to study the process of extracting metals Fe, Zn, and Al in the mineral pyrite using bioleaching process, and specifically aims to determine the effect of time and type of microorganisms based on the concentration and yield of the extraction and to study the effect of microorganisms on the selectivity of the metals extracted in the process of the mineral pyrite bioleaching. Parameters used are microorganisms volume (20% of the total volume of work), bioleaching temperature (35°C), the speed of stirrer (70 rpm) and time of bioleaching (10, 20, and 30 days); the type of the analyzed metal are Al, Zn, Fe; and the type of microorganism are Thiobacillus ferooxidans bacteria and Aspergillus niger fungi. The used analysis are AAS and ICP / MS. The result revealed that the time of bioleaching makes some effect on metal concentration in rafinat.The longer time of bioleaching can give the greater value on metal concentration in rafinat. The highest metal concentrations in the rafinat obtained at 759 ppm for the Al using a Thiobacillus ferooxidans bacteria. The highest yield in the rafinat obtained at 15,021% for the Zn using a Thiobacillus ferooxidans bacteria. Generally, Thiobacillus ferooxidans bacteria is better for extracting metals; Fe, Zn, and Al.
Adsorpsi Ion Mn(II) Pada Zeolit yang Disintesis dari Abu Dasar Batubara Termodifikasi Ditizon Riandy Putra
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2015: Prosiding SNTKK 2015
Publisher : Seminar Nasional Teknik Kimia Kejuangan

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Abstract

Adsorption characteristic of Mn(II) on zeolite synthesized from bottom ash with alkaline hydrothermal conditions loaded with dithizone have been examined. The parameters studied includes effect of pH, contact time, initial concentrations and temperature of Mn(II) by batch experiments. The raw and modified samples were characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD), Fourier transformation infra red (FT-IR) and Surface area analyzer (SAA) and used for the removal of Mn(II) from aqueous solution. This research shows Si and Al contents of the bottom ash analysed by XRF spectrometry dominant were used for the alkaline hydrothermal conversion of the bottom ash compounds into zeolite with range SiO2/Al2O3 ratio obtained from 1 to 5. The results of XRD and FTIR showed that the activation with reflux of bottom ash by alkali hydrothermal process can produce a material which has a similar structure zeolite (zeolite-like). Hydrothermal product consists of a mixture of zeolite (zeolite Y, zeolite Na-P and zeolite X) and sodalite crystals at temperatures of 100 °C for 24 hours. Hydrothermal product showed specific IR absorption zeolite at wavenumber 300-1250 cm-1and zeolite modified dithizone showed absorption -NH and –SH at wavenumber 1496,76 and 2461,17 cm-1. The results SAA showed that with addition dithizone lowering the specific surface area of zeolite from 160,262 m²/g to 69,609 m²/g. Results of study show that adsorption of Mn(II) reaches its maximum values at pH 6 for zeolite and pH 8 for zeolite modified dithizone, respectively. The adsorption kinetics based on the pseudo-second-order rate equation indicates that the rate limiting step involving a chemical reaction. The adsorption rate constants for zeolite synthesis -0,014g/mg.min-1and for the zeolite modified dithizone 0,0204g/mg.min-1. Based on the Langmuir equation, the maximum adsorption capacity (qmax) synthetic zeolite of 2.63x10-4mol/g and zeolite modified dhitizone 2.88x10-4mol/g. Adsorption equilibrium constant for the synthetic zeolite 0,742 mg/L and for zeolite modified dithizone 2,625 mg/L. The negative ΔH and ΔS indicate an exothermic and spontaneous process. But value of ΔG is positive, which indicates that the reaction is not spontaneous. So, adsorption using two adsorbents takes place spontaneously at a lower temperature. In general, the ability of dithizone-loaded zeolite to adsorb Mn(II) is better than does the unmodified one.
Pengaruh Penambahan Diethylene Glycol Terhadap Gas Hasil Fermentasi Limbah Peternakan Sapi Dusun Ngentak, Desa Poncosari, Kecamatan Srandakan, Kabupaten Bantul, DIY Hongki Budi Prasetyo
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2015: Prosiding SNTKK 2015
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Abstract

This study was conducted to determine the effect of the use of diethylene gycol to reduce the water content of the gas produced from waste fermentation of cows cattle in Ngentak, Poncosari Village , Srandakan , Bantu . The steps will be done in this research are to conduct a site survey and gas testing samples using diethylene glycol with a concentration of 90 %. Testing is done by spraying diethlylene glycol into the gas flow through the gas flow pipe connection manually. From the test results indicate that the diethylene glycol can be used to reduce the water content in the gases from waste fermentation of the dairy farms.
The Influence Of Pyrolysis Temperature And Time To The Yield And Quality of Rubber Fruit (Hevea brasiliensis) Shell Liquid Smoke Haris Fadillah
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2015: Prosiding SNTKK 2015
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Rubber development in South Kalimantan is growing rapidly. In 2011, rubber plantations have reached anarea of 226.706 ha. Rubber plantation produces waste in  the form of unprocessed fruit shells. One of the ways to increase the value of rubber fruit shells waste wasby pyrolysis processing. Pyrolysis produced products such as liquid smoke, tar, and charcoal. The purpose of this study was to analyze the effect of pyrolysis temperature and time to the yield and quality of rubber fruit shellliquid smoke and determine the best treatment of the pyrolysis liquid smoke processing. Pyrolysis process of rubber fruit shell was processed at 200°C, 300°C, 400°C for 1 and 2 hours. Pyrolysis reactor that used was 10 kg capacity. The pyrolysis at 200 °C for 2 hour was the optimum process condition to produce the best liquid smoke with 36.05±0.90 % (w/w) of liquid smoke yield, 3.48 ±0.22 % (w/w) of tar yield, 15,35±1,16 % (w/w) of weight lo ss, and 45.13±0.38 % (w/w) of charcoal yield, and t he quality of the liquid smoke were pH of 2.495±0.050, acid le vels 13.71±0.51 %, total phenols 1.47±0.03 %, and c olor levels 5R 3/10.
Pengolahan Limbah Plastik Kemasan Multilayer Ldpe (Low Density Poly Ethilene) dengan Menggunakan Metode Pirolisis Microwave SR Juliastuti
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2015: Prosiding SNTKK 2015
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Abstract

Increased energy consumption and waste generation are two problems that rise due to economic and population growth. To overcome the problem, especially plastic waste, environmental experts and scientists from various disciplines have conducted various studies and actions. One way is to degrade the Low Density Polyethylene plastic waste multilayer packaging by microwave pyrolysis. The purpose is to determine the effect of temperature and time when degrading the LDPE plastics waste by microwave pyrolysis. The processes done with operating condition of pressure at 1 atm and nitrogen flowed at 0.5 L / min in glass reactor. Samples are used as much as 60 grams of LDPE plastics. The sample is heated to a temperature of 250, 350, and 500°C it’s maintained at variable time for 10, 30, and 60 minutes. Liquid products were analyzed by gas chromatography-mass spectrometry (GC-MS), non-condensable gas was analyzed by gas chromatography (GC), raw material samples were analyzed using Fourier Transform Infrared (FTIR) and calculating the yield of liquid products, solid and concentration of gas. From the experimental results are obtained that microwave pyrolysis best operating conditions is at 500oC of 60 minutes with 4.67% yield of solid, 23.65% liquid, and concentration of CH4 30.41%.