Anawati Anawati
Departemen Fisika, FMIPA, Universitas Indonesia

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Literature Review−Effect of Additives and Post-Treatments on Corrosion Resistance and Mechanical Properties of Plasma Electrolytic Oxidation Products in Magnesium and Titanium Sri Rahmadani; Anawati Anawati
INDONESIAN JOURNAL OF APPLIED PHYSICS Vol 14, No 2 (2024): October
Publisher : Department of Physics, Sebelas Maret University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.13057/ijap.v14i2.73616

Abstract

Plasma Electrolytic Oxidation (PEO) is a method of converting metal surfaces into an oxide layer with the help of plasma to improve the surface mechanical properties and corrosion resistance of metals. A PEO layer of about 10-50 μm is obtained quickly from 1 second-10 minutes at a voltage range of 150-500 V with AC or DC mode. Characteristics of the outer layer of PEO have pores and cracks, while the inner layer is relatively denser. Cracks and pores reduce the corrosion resistance and mechanical properties of the coating. In this study, a literature search was carried out on the effect of adding additives and post-treatment on the characteristics of PEO coatings grown on magnesium (Mg) and titanium (Ti) metals for biomedical applications. Mg and Ti metals have opposite chemical properties; Mg is a reactive metal, while Ti is an inert metal. Comparing the behavior of the PEO process and the coating produced by the two different metals is absorbing and necessary to understand the fundamentals of the PEO process. The results of a literature search show that the addition of additives increases the growth rate of the coating so that the coating is thicker and more wear resistant. The hardness of the coating also increases due to the additive particles trapped in the oxide layer filling the micro pores so that the surface becomes denser and more homogeneous. Therefore, corrosion resistance also increases, as indicated by a decrease in corrosion current as measured by the polarization test and an increase in the impedance modulus as measured by the electrochemical impedance test (EIS). The post-alkali treatment allows for increased surface bioactivity, as indicated by the rise in the Ca/P ratio after immersion in a physiological solution.
Review of Electrical Parameters Influence on Characteristics of Plasma Electrolytic Oxide Coating on Zircaloy Fajar Al Afghani; Anawati Anawati
INDONESIAN JOURNAL OF APPLIED PHYSICS Vol 14, No 2 (2024): October
Publisher : Department of Physics, Sebelas Maret University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.13057/ijap.v14i2.70654

Abstract

Zircaloy-4 (Zr-4) is used as a fuel cladding material in Pressurized Water Reactor (PWR). Zr-4 as a cladding material works in extreme conditions in pressurized water up to 150 atm at 325 ˚C. In addition, the refuelling process in the reactor requires surface protection of the clay material to minimize corrosion and wear. One of the raising methods to enhance the corrosion resistance of the Zr-4 is by plasma electrolytic oxidation (PEO). Characteristics of the ceramic oxide layer produced by PEO are influenced by current density, type and composition of the electrolyte, and voltage mode. One of the challenges in the PEO development on the Zr-4 substrate is a high porosity with a range of 5%-20% and the low number (below 6%) of t-ZrO2 phases in the inner and outer layers. Optimizing the electrical parameters is necessary to overcome this problem. The results of the literature study show that the cathodic current at the AC voltage plays an important role in determining the resulting plasma characteristics. Low duty cycle (cathodic current> 50%) produce plasma with high density, resulting in a low porosity layer. Oppositely, high duty cycle (cathodic current <50%) produced high content of t-ZrO2 increase the mechanical resistance. Two-step PEO is beneficial in combining the low and high duty cycle to obtain the benefit of each step.