The rapid adoption of microservices architectures and cloud-native technologies has significantly transformed modern software delivery practices while simultaneously increasing operational complexity across enterprise environments. Although DevOps methodologies have improved collaboration between development and operations teams and accelerated software release cycles, organizations operating at scale frequently encounter challenges such as fragmented tooling ecosystems, duplicated automation workflows, inconsistent infrastructure governance, and growing cognitive burdens on development teams. These challenges become particularly pronounced in enterprises managing hundreds of development teams and thousands of distributed services. In response, Platform Engineering has emerged as a strategic evolution of DevOps, introducing Internal Developer Platforms (IDPs) that provide standardized infrastructure capabilities, self-service automation, and enhanced developer experiences. This paper proposes a comprehensive architectural framework for enterprise-scale Platform Engineering environments that integrates Kubernetes-based container orchestration, GitOps-driven deployment models, infrastructure-as-code automation, service catalog management, observability platforms, and developer self-service portals. The study draws upon empirical findings from the DORA State of DevOps research program, the Cloud Native Computing Foundation (CNCF) Platforms White Paper, and established industry reference architectures to identify key design principles and operational requirements for successful platform adoption. The proposed framework introduces a four-layer reference architecture encompassing infrastructure, platform services, developer experience, and governance capabilities. In addition, a five-level capability maturity model is presented to guide organizations in systematically evolving their platform engineering practices. A comprehensive measurement strategy based on DORA performance metrics, platform adoption indicators, and developer experience metrics is also developed to assess operational effectiveness and business value. The findings demonstrate that Platform Engineering can substantially reduce operational complexity, improve software delivery performance, increase developer productivity, strengthen security and compliance governance, and enhance organizational scalability. The framework provides technology leaders with a practical roadmap for implementing sustainable and efficient cloud-native operating models in large-scale enterprise environments.